A model for the structural transformation processes in lead monolayer adsorbate on Ag(111) faces at high coverages

A. Popov; N. Dimitrov; D. Kashchiev; T. Vitanov; E. Budevski

doi:10.1016/0013-4686(93)85155-R

A model for the structural transformation processes in lead monolayer adsorbate on Ag(111) faces at high coverages

A. Popov
, N. Dimitrov
, D. Kashchiev
, T. Vitanov
, E. Budevski

Chemistry

Binghamton University

Bulgarian Academy of Sciences

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A theoretical model is proposed for the transformation processes in Pb monolayers of high coverages, underpotentially adsorbed on Ag(111). The basic assumption is that these processes are due to one-dimensional diffusion from a thin layer which under the experimental conditions is represented by the monolayer of adsorbed Pb atoms. The results of the model are in good agreement with previous experimental data. Several kinetic and energy parameters describing the transformation process are determined.

Original language	English
Pages (from-to)	387-391
Number of pages	5
Journal	Electrochimica Acta
Volume	38
Issue number	2-3
DOIs	https://doi.org/10.1016/0013-4686(93)85155-R
State	Published - Feb 1993

Keywords

UPD
silver single crystal
transformations.

Access to Document

10.1016/0013-4686(93)85155-R

Cite this

@article{b237193ee7914838bd600fcc377c488c,

title = "A model for the structural transformation processes in lead monolayer adsorbate on Ag(111) faces at high coverages",

abstract = "A theoretical model is proposed for the transformation processes in Pb monolayers of high coverages, underpotentially adsorbed on Ag(111). The basic assumption is that these processes are due to one-dimensional diffusion from a thin layer which under the experimental conditions is represented by the monolayer of adsorbed Pb atoms. The results of the model are in good agreement with previous experimental data. Several kinetic and energy parameters describing the transformation process are determined.",

keywords = "UPD, silver single crystal, transformations.",

author = "A. Popov and N. Dimitrov and D. Kashchiev and T. Vitanov and E. Budevski",

year = "1993",

month = feb,

doi = "10.1016/0013-4686(93)85155-R",

language = "English",

volume = "38",

pages = "387--391",

journal = "Electrochimica Acta",

issn = "0013-4686",

publisher = "Elsevier Ltd",

number = "2-3",

}

TY - JOUR

T1 - A model for the structural transformation processes in lead monolayer adsorbate on Ag(111) faces at high coverages

AU - Popov, A.

AU - Dimitrov, N.

AU - Kashchiev, D.

AU - Vitanov, T.

AU - Budevski, E.

PY - 1993/2

Y1 - 1993/2

N2 - A theoretical model is proposed for the transformation processes in Pb monolayers of high coverages, underpotentially adsorbed on Ag(111). The basic assumption is that these processes are due to one-dimensional diffusion from a thin layer which under the experimental conditions is represented by the monolayer of adsorbed Pb atoms. The results of the model are in good agreement with previous experimental data. Several kinetic and energy parameters describing the transformation process are determined.

AB - A theoretical model is proposed for the transformation processes in Pb monolayers of high coverages, underpotentially adsorbed on Ag(111). The basic assumption is that these processes are due to one-dimensional diffusion from a thin layer which under the experimental conditions is represented by the monolayer of adsorbed Pb atoms. The results of the model are in good agreement with previous experimental data. Several kinetic and energy parameters describing the transformation process are determined.

KW - UPD

KW - silver single crystal

KW - transformations.

UR - https://www.scopus.com/pages/publications/23544459059

U2 - 10.1016/0013-4686(93)85155-R

DO - 10.1016/0013-4686(93)85155-R

M3 - Article

SN - 0013-4686

VL - 38

SP - 387

EP - 391

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 2-3

ER -

A model for the structural transformation processes in lead monolayer adsorbate on Ag(111) faces at high coverages

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this