A new synthetic route towards a Ru(III) substituted heteropolytungstate anion

Claire Besson; Su Wen Chen; Richard Villanneau; Guillaume Izzet; Anna Proust

doi:10.1016/j.inoche.2009.08.016

A new synthetic route towards a Ru(III) substituted heteropolytungstate anion

Claire Besson
, Su Wen Chen
, Richard Villanneau
, Guillaume Izzet
, Anna Proust

Chemistry

Binghamton University

Université Pierre et Marie Curie Univ. Paris 06

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Microwave irradiation of a mixture of K₇[PW₁₁O₃₉]·14H₂O and [Ru(dmf)₆](CF₃SO₃)₃ allowed the straightforward hydrothermal synthesis of the Keggin-type [PW₁₁O₃₉Ru^III(OH₂)]^4- anion. Physical characterizations of the corresponding tetrabutylammonium (TBA) salt are herein described. This study provides a complete set of spectroscopic and electrochemical references for Ru^III-incorporating heteropolytungstates.

Original language	English
Pages (from-to)	1042-1044
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	12
Issue number	10
DOIs	https://doi.org/10.1016/j.inoche.2009.08.016
State	Published - Oct 2009

Keywords

EPR spectroscopy
Microwave activation
Polyoxometalates
Ruthenium
XANES

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10.1016/j.inoche.2009.08.016

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@article{e2fbbb4d0fad4def8a79f0d27a2a83e5,

title = "A new synthetic route towards a Ru(III) substituted heteropolytungstate anion",

abstract = "Microwave irradiation of a mixture of K7[PW11O39]·14H2O and [Ru(dmf)6](CF3SO3)3 allowed the straightforward hydrothermal synthesis of the Keggin-type [PW11O39RuIII(OH2)]4- anion. Physical characterizations of the corresponding tetrabutylammonium (TBA) salt are herein described. This study provides a complete set of spectroscopic and electrochemical references for RuIII-incorporating heteropolytungstates.",

keywords = "EPR spectroscopy, Microwave activation, Polyoxometalates, Ruthenium, XANES",

author = "Claire Besson and Chen, \{Su Wen\} and Richard Villanneau and Guillaume Izzet and Anna Proust",

year = "2009",

month = oct,

doi = "10.1016/j.inoche.2009.08.016",

language = "English",

volume = "12",

pages = "1042--1044",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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}

TY - JOUR

T1 - A new synthetic route towards a Ru(III) substituted heteropolytungstate anion

AU - Besson, Claire

AU - Chen, Su Wen

AU - Villanneau, Richard

AU - Izzet, Guillaume

AU - Proust, Anna

PY - 2009/10

Y1 - 2009/10

N2 - Microwave irradiation of a mixture of K7[PW11O39]·14H2O and [Ru(dmf)6](CF3SO3)3 allowed the straightforward hydrothermal synthesis of the Keggin-type [PW11O39RuIII(OH2)]4- anion. Physical characterizations of the corresponding tetrabutylammonium (TBA) salt are herein described. This study provides a complete set of spectroscopic and electrochemical references for RuIII-incorporating heteropolytungstates.

AB - Microwave irradiation of a mixture of K7[PW11O39]·14H2O and [Ru(dmf)6](CF3SO3)3 allowed the straightforward hydrothermal synthesis of the Keggin-type [PW11O39RuIII(OH2)]4- anion. Physical characterizations of the corresponding tetrabutylammonium (TBA) salt are herein described. This study provides a complete set of spectroscopic and electrochemical references for RuIII-incorporating heteropolytungstates.

KW - EPR spectroscopy

KW - Microwave activation

KW - Polyoxometalates

KW - Ruthenium

KW - XANES

UR - https://www.scopus.com/pages/publications/70349432161

U2 - 10.1016/j.inoche.2009.08.016

DO - 10.1016/j.inoche.2009.08.016

M3 - Article

SN - 1387-7003

VL - 12

SP - 1042

EP - 1044

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 10

ER -

A new synthetic route towards a Ru(III) substituted heteropolytungstate anion

Abstract

Keywords

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