A study of the Li |Lixv2O4 cell

Eugen P. Koval'chuk; Olexander V. Reshetnyak; M. Stanley Whittingham; Peter Y. Zavalij; Ihor Yu Zavaliy

A study of the Li |Li_xv₂O₄ cell

Eugen P. Koval'chuk
, Olexander V. Reshetnyak
, M. Stanley Whittingham
, Peter Y. Zavalij
, Ihor Yu Zavaliy

Chemistry

Binghamton University

Research output: Contribution to journal › Article › peer-review

Abstract

The studies of the Li|1M LiClO₄ in propylene carbonate |Li_xV₂O₄ cell were carried out. The results of the electrochemical and X-ray investigations indicated that the cathode reaction in this cell proceeds as an intercalation process. Cycling test shows the reversibility of this cell along 35 charge/discharge cycles. However X-ray diffraction of the electrode material shows partial oxidizing of the Li_xV₂O₄ phase yielding γ-LiV₂O₅. The kinetic parameters of this process such as the chemical diffusion coefficient and mobility of lithium in the Li_xV₂O₄ were calculated.

Original language	English
Pages (from-to)	239-244
Number of pages	6
Journal	Materials Research Society Symposium - Proceedings
Volume	548
State	Published - 1999

Cite this

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title = "A study of the Li |Lixv2O4 cell",

abstract = "The studies of the Li|1M LiClO4 in propylene carbonate |LixV2O4 cell were carried out. The results of the electrochemical and X-ray investigations indicated that the cathode reaction in this cell proceeds as an intercalation process. Cycling test shows the reversibility of this cell along 35 charge/discharge cycles. However X-ray diffraction of the electrode material shows partial oxidizing of the LixV2O4 phase yielding γ-LiV2O5. The kinetic parameters of this process such as the chemical diffusion coefficient and mobility of lithium in the LixV2O4 were calculated.",

author = "Koval'chuk, \{Eugen P.\} and Reshetnyak, \{Olexander V.\} and Whittingham, \{M. Stanley\} and Zavalij, \{Peter Y.\} and Zavaliy, \{Ihor Yu\}",

year = "1999",

language = "English",

volume = "548",

pages = "239--244",

journal = "Materials Research Society Symposium - Proceedings",

issn = "0272-9172",

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TY - JOUR

T1 - A study of the Li |Lixv2O4 cell

AU - Koval'chuk, Eugen P.

AU - Reshetnyak, Olexander V.

AU - Whittingham, M. Stanley

AU - Zavalij, Peter Y.

AU - Zavaliy, Ihor Yu

PY - 1999

Y1 - 1999

N2 - The studies of the Li|1M LiClO4 in propylene carbonate |LixV2O4 cell were carried out. The results of the electrochemical and X-ray investigations indicated that the cathode reaction in this cell proceeds as an intercalation process. Cycling test shows the reversibility of this cell along 35 charge/discharge cycles. However X-ray diffraction of the electrode material shows partial oxidizing of the LixV2O4 phase yielding γ-LiV2O5. The kinetic parameters of this process such as the chemical diffusion coefficient and mobility of lithium in the LixV2O4 were calculated.

AB - The studies of the Li|1M LiClO4 in propylene carbonate |LixV2O4 cell were carried out. The results of the electrochemical and X-ray investigations indicated that the cathode reaction in this cell proceeds as an intercalation process. Cycling test shows the reversibility of this cell along 35 charge/discharge cycles. However X-ray diffraction of the electrode material shows partial oxidizing of the LixV2O4 phase yielding γ-LiV2O5. The kinetic parameters of this process such as the chemical diffusion coefficient and mobility of lithium in the LixV2O4 were calculated.

UR - https://www.scopus.com/pages/publications/0033338082

M3 - Article

SN - 0272-9172

VL - 548

SP - 239

EP - 244

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

ER -

A study of the Li |Li_xv₂O₄ cell

Abstract

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