Alkylldyne-Alkyne Coupling on Trlruthenlum Clusters. A Potential Model for Flscher-Tropsch Chain Growth

Lawrence R. Beanan; Zuraldah Abdul Rahman; Jerome B. Kelster

doi:10.1021/om50002a029

Alkylldyne-Alkyne Coupling on Trlruthenlum Clusters. A Potential Model for Flscher-Tropsch Chain Growth

Lawrence R. Beanan
, Zuraldah Abdul Rahman
, Jerome B. Kelster

Chemistry

University at Buffalo

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

The clusters H₃Ru₃(μ₃-CX)(CO)₉ (X = OMe, Me, Ph) react with alkynes C₂R₂ to form the corresponding alkene C₂H₂R₂ and HRu₃(μ₃-η³-CXCRCR)(CO)₉. Terminal alkynes yield mixtures of the two possible isomers in ratios dependent upon the steric bulk of the substituent. Hydrogenation of HRu₃(μ₃-η³-C(OMe)CRCR)(CO)₉ yields the corresponding H₃Ru₃(μ₃-CCHRCH₂R)(CO)₉.

Original language	English
Pages (from-to)	1062-1064
Number of pages	3
Journal	Organometallics
Volume	2
Issue number	8
DOIs	https://doi.org/10.1021/om50002a029
State	Published - Aug 1983

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@article{a3e0eda7d1164585b0021ec6402b3191,

title = "Alkylldyne-Alkyne Coupling on Trlruthenlum Clusters. A Potential Model for Flscher-Tropsch Chain Growth",

abstract = "The clusters H3Ru3(μ3-CX)(CO)9 (X = OMe, Me, Ph) react with alkynes C2R2 to form the corresponding alkene C2H2R2 and HRu3(μ3-η3-CXCRCR)(CO)9. Terminal alkynes yield mixtures of the two possible isomers in ratios dependent upon the steric bulk of the substituent. Hydrogenation of HRu3(μ3-η3-C(OMe)CRCR)(CO)9 yields the corresponding H3Ru3(μ3-CCHRCH2R)(CO)9.",

author = "Beanan, \{Lawrence R.\} and Rahman, \{Zuraldah Abdul\} and Kelster, \{Jerome B.\}",

year = "1983",

month = aug,

doi = "10.1021/om50002a029",

language = "English",

volume = "2",

pages = "1062--1064",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "8",

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TY - JOUR

T1 - Alkylldyne-Alkyne Coupling on Trlruthenlum Clusters. A Potential Model for Flscher-Tropsch Chain Growth

AU - Beanan, Lawrence R.

AU - Rahman, Zuraldah Abdul

AU - Kelster, Jerome B.

PY - 1983/8

Y1 - 1983/8

N2 - The clusters H3Ru3(μ3-CX)(CO)9 (X = OMe, Me, Ph) react with alkynes C2R2 to form the corresponding alkene C2H2R2 and HRu3(μ3-η3-CXCRCR)(CO)9. Terminal alkynes yield mixtures of the two possible isomers in ratios dependent upon the steric bulk of the substituent. Hydrogenation of HRu3(μ3-η3-C(OMe)CRCR)(CO)9 yields the corresponding H3Ru3(μ3-CCHRCH2R)(CO)9.

AB - The clusters H3Ru3(μ3-CX)(CO)9 (X = OMe, Me, Ph) react with alkynes C2R2 to form the corresponding alkene C2H2R2 and HRu3(μ3-η3-CXCRCR)(CO)9. Terminal alkynes yield mixtures of the two possible isomers in ratios dependent upon the steric bulk of the substituent. Hydrogenation of HRu3(μ3-η3-C(OMe)CRCR)(CO)9 yields the corresponding H3Ru3(μ3-CCHRCH2R)(CO)9.

UR - https://www.scopus.com/pages/publications/0012844330

U2 - 10.1021/om50002a029

DO - 10.1021/om50002a029

M3 - Article

SN - 0276-7333

VL - 2

SP - 1062

EP - 1064

JO - Organometallics

JF - Organometallics

IS - 8

ER -

Alkylldyne-Alkyne Coupling on Trlruthenlum Clusters. A Potential Model for Flscher-Tropsch Chain Growth

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