Alternating ring-opening metathesis polymerization copolymers containing charge-transfer units

Joy Romulus; Li Tan; Marcus Weck; Nicole S. Sampson

doi:10.1021/mz4002673

Alternating ring-opening metathesis polymerization copolymers containing charge-transfer units

Joy Romulus
, Li Tan
, Marcus Weck
, Nicole S. Sampson

Chemistry

Stony Brook University

New York University
Stony Brook University

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Alternating copolymers derived from the ring-opening metathesis polymerization (ROMP) of functionalized cyclobutene esters (CBEs) and cyclohexenes (CHs) are described. The copolymer poly(CBE-alt-CH)_n contains alternating side chains based on dialkoxynaphthalene (DAN) and pyromellitic dianhydride (PDI). Characterization by UV-vis spectroscopy showed that the copolymers exhibit an increase in charge-transfer intensity in comparison to previously reported alternating copolymers. The bulky side chains inhibit backbiting during the polymerization and allow for enhanced control over the polymerization in comparison to copolymers functionalized with linear alkyl groups.

Original language	English
Pages (from-to)	749-752
Number of pages	4
Journal	ACS Macro Letters
Volume	2
Issue number	8
DOIs	https://doi.org/10.1021/mz4002673
State	Published - Aug 20 2013

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title = "Alternating ring-opening metathesis polymerization copolymers containing charge-transfer units",

abstract = "Alternating copolymers derived from the ring-opening metathesis polymerization (ROMP) of functionalized cyclobutene esters (CBEs) and cyclohexenes (CHs) are described. The copolymer poly(CBE-alt-CH)n contains alternating side chains based on dialkoxynaphthalene (DAN) and pyromellitic dianhydride (PDI). Characterization by UV-vis spectroscopy showed that the copolymers exhibit an increase in charge-transfer intensity in comparison to previously reported alternating copolymers. The bulky side chains inhibit backbiting during the polymerization and allow for enhanced control over the polymerization in comparison to copolymers functionalized with linear alkyl groups.",

author = "Joy Romulus and Li Tan and Marcus Weck and Sampson, \{Nicole S.\}",

year = "2013",

month = aug,

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doi = "10.1021/mz4002673",

language = "English",

volume = "2",

pages = "749--752",

journal = "ACS Macro Letters",

issn = "2161-1653",

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T1 - Alternating ring-opening metathesis polymerization copolymers containing charge-transfer units

AU - Romulus, Joy

AU - Tan, Li

AU - Weck, Marcus

AU - Sampson, Nicole S.

PY - 2013/8/20

Y1 - 2013/8/20

N2 - Alternating copolymers derived from the ring-opening metathesis polymerization (ROMP) of functionalized cyclobutene esters (CBEs) and cyclohexenes (CHs) are described. The copolymer poly(CBE-alt-CH)n contains alternating side chains based on dialkoxynaphthalene (DAN) and pyromellitic dianhydride (PDI). Characterization by UV-vis spectroscopy showed that the copolymers exhibit an increase in charge-transfer intensity in comparison to previously reported alternating copolymers. The bulky side chains inhibit backbiting during the polymerization and allow for enhanced control over the polymerization in comparison to copolymers functionalized with linear alkyl groups.

AB - Alternating copolymers derived from the ring-opening metathesis polymerization (ROMP) of functionalized cyclobutene esters (CBEs) and cyclohexenes (CHs) are described. The copolymer poly(CBE-alt-CH)n contains alternating side chains based on dialkoxynaphthalene (DAN) and pyromellitic dianhydride (PDI). Characterization by UV-vis spectroscopy showed that the copolymers exhibit an increase in charge-transfer intensity in comparison to previously reported alternating copolymers. The bulky side chains inhibit backbiting during the polymerization and allow for enhanced control over the polymerization in comparison to copolymers functionalized with linear alkyl groups.

UR - https://www.scopus.com/pages/publications/84883062348

U2 - 10.1021/mz4002673

DO - 10.1021/mz4002673

M3 - Article

SN - 2161-1653

VL - 2

SP - 749

EP - 752

JO - ACS Macro Letters

JF - ACS Macro Letters

IS - 8

ER -

Alternating ring-opening metathesis polymerization copolymers containing charge-transfer units

Abstract

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