Atom economy in the metathesis cross-coupling of alkenes and alkynes

Joseph R. Clark; Steven T. Diver

doi:10.1021/ol200914j

Atom economy in the metathesis cross-coupling of alkenes and alkynes

Joseph R. Clark
, Steven T. Diver

Chemistry

University at Buffalo

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

A cross ene-yne metathesis has been achieved at a nearly 1:1 stoichiometry of the unsaturated reactants. This allowed the use of more complex alkene reactants without sacrificing excess alkene reactant. In the alkene, different allylic oxygen protecting groups were explored. Interestingly, alkenes containing the allylic hydroxyl group proved to be the most reactive.

Original language	English
Pages (from-to)	2896-2899
Number of pages	4
Journal	Organic Letters
Volume	13
Issue number	11
DOIs	https://doi.org/10.1021/ol200914j
State	Published - Jun 3 2011

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10.1021/ol200914j

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title = "Atom economy in the metathesis cross-coupling of alkenes and alkynes",

abstract = "A cross ene-yne metathesis has been achieved at a nearly 1:1 stoichiometry of the unsaturated reactants. This allowed the use of more complex alkene reactants without sacrificing excess alkene reactant. In the alkene, different allylic oxygen protecting groups were explored. Interestingly, alkenes containing the allylic hydroxyl group proved to be the most reactive.",

author = "Clark, \{Joseph R.\} and Diver, \{Steven T.\}",

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AU - Diver, Steven T.

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N2 - A cross ene-yne metathesis has been achieved at a nearly 1:1 stoichiometry of the unsaturated reactants. This allowed the use of more complex alkene reactants without sacrificing excess alkene reactant. In the alkene, different allylic oxygen protecting groups were explored. Interestingly, alkenes containing the allylic hydroxyl group proved to be the most reactive.

AB - A cross ene-yne metathesis has been achieved at a nearly 1:1 stoichiometry of the unsaturated reactants. This allowed the use of more complex alkene reactants without sacrificing excess alkene reactant. In the alkene, different allylic oxygen protecting groups were explored. Interestingly, alkenes containing the allylic hydroxyl group proved to be the most reactive.

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U2 - 10.1021/ol200914j

DO - 10.1021/ol200914j

M3 - Article

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VL - 13

SP - 2896

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JO - Organic Letters

JF - Organic Letters

IS - 11

ER -

Atom economy in the metathesis cross-coupling of alkenes and alkynes

Abstract

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