Bifunctional hydrophobic ionic liquids: Facile synthesis by thiol-ene "click" chemistry

Manuel Sanchez Zayas; Jamie C. Gaitor; Stephen T. Nestor; Samuel Minkowicz; Yinghong Sheng; Arsalan Mirjafari

doi:10.1039/c5gc01930c

Bifunctional hydrophobic ionic liquids: Facile synthesis by thiol-ene "click" chemistry

Manuel Sanchez Zayas
, Jamie C. Gaitor
, Stephen T. Nestor
, Samuel Minkowicz
, Yinghong Sheng
, Arsalan Mirjafari

Chemistry

SUNY Oswego

Florida Gulf Coast University

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

We describe the facile, robust and orthogonal fabrication of a structurally comprehensive library of hydrophobic trimethoxysilyl-functionalized ionic liquids with C₇-C₁₅ thioether spacer, using thiol-ene "click" chemistry. The synthesized ionic liquids displayed very low glass transition temperatures, high thermal stability and were hydrophobic in character. And the ability to serve as surface coating agents was tested by immobilizing them on the surface of iron oxide supermagnetic nanoparticles and the organic loadings were quantified.

Original language	English
Pages (from-to)	2443-2452
Number of pages	10
Journal	Green Chemistry
Volume	18
Issue number	8
DOIs	https://doi.org/10.1039/c5gc01930c
State	Published - Apr 21 2016

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abstract = "We describe the facile, robust and orthogonal fabrication of a structurally comprehensive library of hydrophobic trimethoxysilyl-functionalized ionic liquids with C7-C15 thioether spacer, using thiol-ene {"}click{"} chemistry. The synthesized ionic liquids displayed very low glass transition temperatures, high thermal stability and were hydrophobic in character. And the ability to serve as surface coating agents was tested by immobilizing them on the surface of iron oxide supermagnetic nanoparticles and the organic loadings were quantified.",

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AU - Nestor, Stephen T.

AU - Minkowicz, Samuel

AU - Sheng, Yinghong

AU - Mirjafari, Arsalan

PY - 2016/4/21

Y1 - 2016/4/21

N2 - We describe the facile, robust and orthogonal fabrication of a structurally comprehensive library of hydrophobic trimethoxysilyl-functionalized ionic liquids with C7-C15 thioether spacer, using thiol-ene "click" chemistry. The synthesized ionic liquids displayed very low glass transition temperatures, high thermal stability and were hydrophobic in character. And the ability to serve as surface coating agents was tested by immobilizing them on the surface of iron oxide supermagnetic nanoparticles and the organic loadings were quantified.

AB - We describe the facile, robust and orthogonal fabrication of a structurally comprehensive library of hydrophobic trimethoxysilyl-functionalized ionic liquids with C7-C15 thioether spacer, using thiol-ene "click" chemistry. The synthesized ionic liquids displayed very low glass transition temperatures, high thermal stability and were hydrophobic in character. And the ability to serve as surface coating agents was tested by immobilizing them on the surface of iron oxide supermagnetic nanoparticles and the organic loadings were quantified.

UR - https://www.scopus.com/pages/publications/84966341104

U2 - 10.1039/c5gc01930c

DO - 10.1039/c5gc01930c

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JO - Green Chemistry

JF - Green Chemistry

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ER -

Bifunctional hydrophobic ionic liquids: Facile synthesis by thiol-ene "click" chemistry

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