Bimetallic sulfates A2M(SO4)2· nH2O (A = Li, Na and M = transition metal) as new attractive electrode materials for Li- and Na-ion batteries

M. Reynaud; M. Ati; S. Boulineau; M. T. Sougrati; B. C. Melot; G. Rousse; J. N. Chotard; J. M. Tarascona

doi:10.1149/05024.0011ecst

Bimetallic sulfates A₂M(SO₄)₂· nH₂O (A = Li, Na and M = transition metal) as new attractive electrode materials for Li- and Na-ion batteries

M. Reynaud
, M. Ati
, S. Boulineau
, M. T. Sougrati
, B. C. Melot
, G. Rousse
, J. N. Chotard
, J. M. Tarascona

Chemistry

Binghamton University

Université de Picardie Jules Verne
Institut Charles Gerhardt Montpellier
Institut de Minéralogie et de Physique des Milieux Condensés

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

34 Scopus citations

Abstract

Developing the next generations of Li- and Na-ion batteries relies on designing new sustainable, low-cost and safe electrode materials. In such an attempt, we investigated several series of bimetallic sulfates, among them we identified Na₂Fe(SO₄) ₂·₄H₂O, Na₂Fe(SO ₄)₂ and Li₂Fe(SO₄)₂, which present attractive electrochemical properties against both lithium and sodium. With a potential of 3.83 V vs. Li⁺/Li⁰, the new lithium iron sulfate Li₂Fe(SO₄)₂ displays indeed the highest potential ever obtained for the Fe³⁺/Fe ²⁺ redox couple in an iron-based fluorine-free compound.

Original language	English
Title of host publication	Intercalation Compounds for Rechargeable Batteries
Publisher	Electrochemical Society Inc.
Pages	11-19
Number of pages	9
Edition	24
ISBN (Print)	9781607684121
DOIs	https://doi.org/10.1149/05024.0011ecst
State	Published - 2013
Event	Symposium on Intercalation Compounds for Rechargeable Batteries - 222nd ECS Meeting - Honolulu, HI, United States Duration: Oct 7 2012 → Oct 12 2012

Publication series

Name	ECS Transactions
Number	24
Volume	50

Conference

Conference	Symposium on Intercalation Compounds for Rechargeable Batteries - 222nd ECS Meeting
Country/Territory	United States
City	Honolulu, HI
Period	10/7/12 → 10/12/12

Access to Document

10.1149/05024.0011ecst

Cite this

Reynaud, M., Ati, M., Boulineau, S., Sougrati, M. T., Melot, B. C., Rousse, G., Chotard, J. N., & Tarascona, J. M. (2013). Bimetallic sulfates A₂M(SO₄)₂· nH₂O (A = Li, Na and M = transition metal) as new attractive electrode materials for Li- and Na-ion batteries. In Intercalation Compounds for Rechargeable Batteries (24 ed., pp. 11-19). (ECS Transactions; Vol. 50, No. 24). Electrochemical Society Inc.. https://doi.org/10.1149/05024.0011ecst

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title = "Bimetallic sulfates A2M(SO4)2· nH2O (A = Li, Na and M = transition metal) as new attractive electrode materials for Li- and Na-ion batteries",

abstract = "Developing the next generations of Li- and Na-ion batteries relies on designing new sustainable, low-cost and safe electrode materials. In such an attempt, we investigated several series of bimetallic sulfates, among them we identified Na2Fe(SO4) 2·4H2O, Na2Fe(SO 4)2 and Li2Fe(SO4)2, which present attractive electrochemical properties against both lithium and sodium. With a potential of 3.83 V vs. Li+/Li0, the new lithium iron sulfate Li2Fe(SO4)2 displays indeed the highest potential ever obtained for the Fe3+/Fe 2+ redox couple in an iron-based fluorine-free compound.",

author = "M. Reynaud and M. Ati and S. Boulineau and Sougrati, \{M. T.\} and Melot, \{B. C.\} and G. Rousse and Chotard, \{J. N.\} and Tarascona, \{J. M.\}",

year = "2013",

doi = "10.1149/05024.0011ecst",

language = "English",

isbn = "9781607684121",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "24",

pages = "11--19",

booktitle = "Intercalation Compounds for Rechargeable Batteries",

edition = "24",

note = "Symposium on Intercalation Compounds for Rechargeable Batteries - 222nd ECS Meeting ; Conference date: 07-10-2012 Through 12-10-2012",

}

Reynaud, M, Ati, M, Boulineau, S, Sougrati, MT, Melot, BC, Rousse, G, Chotard, JN & Tarascona, JM 2013, Bimetallic sulfates A₂M(SO₄)₂· nH₂O (A = Li, Na and M = transition metal) as new attractive electrode materials for Li- and Na-ion batteries. in Intercalation Compounds for Rechargeable Batteries. 24 edn, ECS Transactions, no. 24, vol. 50, Electrochemical Society Inc., pp. 11-19, Symposium on Intercalation Compounds for Rechargeable Batteries - 222nd ECS Meeting, Honolulu, HI, United States, 10/7/12. https://doi.org/10.1149/05024.0011ecst

Bimetallic sulfates A₂M(SO₄)₂· nH₂O (A = Li, Na and M = transition metal) as new attractive electrode materials for Li- and Na-ion batteries. / Reynaud, M.; Ati, M.; Boulineau, S. et al.
Intercalation Compounds for Rechargeable Batteries. 24. ed. Electrochemical Society Inc., 2013. p. 11-19 (ECS Transactions; Vol. 50, No. 24).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

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AU - Reynaud, M.

AU - Ati, M.

AU - Boulineau, S.

AU - Sougrati, M. T.

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AU - Rousse, G.

AU - Chotard, J. N.

AU - Tarascona, J. M.

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N2 - Developing the next generations of Li- and Na-ion batteries relies on designing new sustainable, low-cost and safe electrode materials. In such an attempt, we investigated several series of bimetallic sulfates, among them we identified Na2Fe(SO4) 2·4H2O, Na2Fe(SO 4)2 and Li2Fe(SO4)2, which present attractive electrochemical properties against both lithium and sodium. With a potential of 3.83 V vs. Li+/Li0, the new lithium iron sulfate Li2Fe(SO4)2 displays indeed the highest potential ever obtained for the Fe3+/Fe 2+ redox couple in an iron-based fluorine-free compound.

AB - Developing the next generations of Li- and Na-ion batteries relies on designing new sustainable, low-cost and safe electrode materials. In such an attempt, we investigated several series of bimetallic sulfates, among them we identified Na2Fe(SO4) 2·4H2O, Na2Fe(SO 4)2 and Li2Fe(SO4)2, which present attractive electrochemical properties against both lithium and sodium. With a potential of 3.83 V vs. Li+/Li0, the new lithium iron sulfate Li2Fe(SO4)2 displays indeed the highest potential ever obtained for the Fe3+/Fe 2+ redox couple in an iron-based fluorine-free compound.

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Reynaud M, Ati M, Boulineau S, Sougrati MT, Melot BC, Rousse G et al. Bimetallic sulfates A₂M(SO₄)₂· nH₂O (A = Li, Na and M = transition metal) as new attractive electrode materials for Li- and Na-ion batteries. In Intercalation Compounds for Rechargeable Batteries. 24 ed. Electrochemical Society Inc. 2013. p. 11-19. (ECS Transactions; 24). doi: 10.1149/05024.0011ecst