Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)tetrakis(μ4-1, 1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraolato)copper(II)octatin(II): A prospective precursor for Cu-doped SnO2 films

Craig M. Lieberman; Alexander S. Filatov; Volodimir D. Vreshch; Evgeny V. Dikarev

doi:10.1107/S0108270113025717

Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)tetrakis(μ₄-1, 1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraolato)copper(II)octatin(II): A prospective precursor for Cu-doped SnO₂ films

Craig M. Lieberman
, Alexander S. Filatov
, Volodimir D. Vreshch
, Evgeny V. Dikarev

Chemistry

University at Albany

SUNY Albany

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The crystal structure of a tin-rich heterometallic supramolecular product, [CuSn₈(C₅HF₆O₂)₂(C ₅H₂F₆O₄)₄] or [Sn ₄(hfpt)₂-Cu(hfac)₂-Sn₄(hfpt) ₂], (I), is reported (hfpt is the tetraanion of 1,1,1,5,5,5- hexafluoropentane-2,2,4,4-tetraol and hfac is the anion of 1,1,1,5,5,5- hexafluoropentane-2,4-dione). Reaction between tin(II) tetraolate, [Sn ₄(hfpt)₂], and copper(II) β-diketonate, [Cu(hfac)₂], was utilized for the preparation of (I). The asymmetric unit consists of the whole [Sn₄(hfpt)₂] unit and half of a [Cu(hfac)₂] unit, with the Cu atom lying on an inversion center. Intermolecular Cu...O interactions from the axial positions of copper in [Cu(hfac)₂] and O atoms of the hfpt ligand in [Sn₄(hfpt) ₂] mediate the formation of a sandwich-type structure for (I). Additional intermolecular Sn...O interactions between neighbouring [Sn ₄(hfpt)₂] units complete a two-dimensional network.

Original language	English
Pages (from-to)	1427-1430
Number of pages	4
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	69
Issue number	12
DOIs	https://doi.org/10.1107/S0108270113025717
State	Published - Dec 2013

Keywords

Crystal structure
Diketonate ligands
Heterometallic copper(II)-tin(II) compounds
Tin(IV) oxide thin films

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10.1107/S0108270113025717

Cite this

Lieberman, C. M., Filatov, A. S., Vreshch, V. D., & Dikarev, E. V. (2013). Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)tetrakis(μ₄-1, 1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraolato)copper(II)octatin(II): A prospective precursor for Cu-doped SnO₂ films. Acta Crystallographica Section C: Crystal Structure Communications, 69(12), 1427-1430. https://doi.org/10.1107/S0108270113025717

@article{cf431a0fb81944f48421d976a7f934f6,

title = "Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)tetrakis(μ4-1, 1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraolato)copper(II)octatin(II): A prospective precursor for Cu-doped SnO2 films",

abstract = "The crystal structure of a tin-rich heterometallic supramolecular product, [CuSn8(C5HF6O2)2(C 5H2F6O4)4] or [Sn 4(hfpt)2-Cu(hfac)2-Sn4(hfpt) 2], (I), is reported (hfpt is the tetraanion of 1,1,1,5,5,5- hexafluoropentane-2,2,4,4-tetraol and hfac is the anion of 1,1,1,5,5,5- hexafluoropentane-2,4-dione). Reaction between tin(II) tetraolate, [Sn 4(hfpt)2], and copper(II) β-diketonate, [Cu(hfac)2], was utilized for the preparation of (I). The asymmetric unit consists of the whole [Sn4(hfpt)2] unit and half of a [Cu(hfac)2] unit, with the Cu atom lying on an inversion center. Intermolecular Cu...O interactions from the axial positions of copper in [Cu(hfac)2] and O atoms of the hfpt ligand in [Sn4(hfpt) 2] mediate the formation of a sandwich-type structure for (I). Additional intermolecular Sn...O interactions between neighbouring [Sn 4(hfpt)2] units complete a two-dimensional network.",

keywords = "Crystal structure, Diketonate ligands, Heterometallic copper(II)-tin(II) compounds, Tin(IV) oxide thin films",

author = "Lieberman, \{Craig M.\} and Filatov, \{Alexander S.\} and Vreshch, \{Volodimir D.\} and Dikarev, \{Evgeny V.\}",

year = "2013",

month = dec,

doi = "10.1107/S0108270113025717",

language = "English",

volume = "69",

pages = "1427--1430",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "John Wiley \& Sons Inc.",

number = "12",

}

Lieberman, CM, Filatov, AS, Vreshch, VD & Dikarev, EV 2013, 'Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)tetrakis(μ₄-1, 1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraolato)copper(II)octatin(II): A prospective precursor for Cu-doped SnO₂ films', Acta Crystallographica Section C: Crystal Structure Communications, vol. 69, no. 12, pp. 1427-1430. https://doi.org/10.1107/S0108270113025717

Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)tetrakis(μ₄-1, 1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraolato)copper(II)octatin(II): A prospective precursor for Cu-doped SnO₂ films. / Lieberman, Craig M.; Filatov, Alexander S.; Vreshch, Volodimir D. et al.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 69, No. 12, 12.2013, p. 1427-1430.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)tetrakis(μ4-1, 1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraolato)copper(II)octatin(II)

T2 - A prospective precursor for Cu-doped SnO2 films

AU - Lieberman, Craig M.

AU - Filatov, Alexander S.

AU - Vreshch, Volodimir D.

AU - Dikarev, Evgeny V.

PY - 2013/12

Y1 - 2013/12

N2 - The crystal structure of a tin-rich heterometallic supramolecular product, [CuSn8(C5HF6O2)2(C 5H2F6O4)4] or [Sn 4(hfpt)2-Cu(hfac)2-Sn4(hfpt) 2], (I), is reported (hfpt is the tetraanion of 1,1,1,5,5,5- hexafluoropentane-2,2,4,4-tetraol and hfac is the anion of 1,1,1,5,5,5- hexafluoropentane-2,4-dione). Reaction between tin(II) tetraolate, [Sn 4(hfpt)2], and copper(II) β-diketonate, [Cu(hfac)2], was utilized for the preparation of (I). The asymmetric unit consists of the whole [Sn4(hfpt)2] unit and half of a [Cu(hfac)2] unit, with the Cu atom lying on an inversion center. Intermolecular Cu...O interactions from the axial positions of copper in [Cu(hfac)2] and O atoms of the hfpt ligand in [Sn4(hfpt) 2] mediate the formation of a sandwich-type structure for (I). Additional intermolecular Sn...O interactions between neighbouring [Sn 4(hfpt)2] units complete a two-dimensional network.

AB - The crystal structure of a tin-rich heterometallic supramolecular product, [CuSn8(C5HF6O2)2(C 5H2F6O4)4] or [Sn 4(hfpt)2-Cu(hfac)2-Sn4(hfpt) 2], (I), is reported (hfpt is the tetraanion of 1,1,1,5,5,5- hexafluoropentane-2,2,4,4-tetraol and hfac is the anion of 1,1,1,5,5,5- hexafluoropentane-2,4-dione). Reaction between tin(II) tetraolate, [Sn 4(hfpt)2], and copper(II) β-diketonate, [Cu(hfac)2], was utilized for the preparation of (I). The asymmetric unit consists of the whole [Sn4(hfpt)2] unit and half of a [Cu(hfac)2] unit, with the Cu atom lying on an inversion center. Intermolecular Cu...O interactions from the axial positions of copper in [Cu(hfac)2] and O atoms of the hfpt ligand in [Sn4(hfpt) 2] mediate the formation of a sandwich-type structure for (I). Additional intermolecular Sn...O interactions between neighbouring [Sn 4(hfpt)2] units complete a two-dimensional network.

KW - Crystal structure

KW - Diketonate ligands

KW - Heterometallic copper(II)-tin(II) compounds

KW - Tin(IV) oxide thin films

UR - https://www.scopus.com/pages/publications/84890066558

U2 - 10.1107/S0108270113025717

DO - 10.1107/S0108270113025717

M3 - Article

C2 - 24311485

SN - 0108-2701

VL - 69

SP - 1427

EP - 1430

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 12

ER -

Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)tetrakis(μ₄-1, 1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraolato)copper(II)octatin(II): A prospective precursor for Cu-doped SnO₂ films

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