Bisphosphine phenol and phenolate complexes of Mn(i): Manganese(i) catalyzed Tishchenko reaction

Karthika J. Kadassery; Samantha N. MacMillan; David C. Lacy

doi:10.1039/c8dt02933d

Bisphosphine phenol and phenolate complexes of Mn(i): Manganese(i) catalyzed Tishchenko reaction

Karthika J. Kadassery
, Samantha N. MacMillan
, David C. Lacy

Chemistry

University at Buffalo

SUNY Buffalo
Cornell University

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

We synthesized new organomanganese complexes using the phenolic "pincer" type ligand H-POP. The coordination chemistry of H-POP with Mn(i) was explored, revealing a wide range of binding motifs. Finally, we found that complex 1 catalyzes the formation of benzyl benzoate from benzaldehyde in a Tishchenko reaction.

Original language	English
Pages (from-to)	12652-12655
Number of pages	4
Journal	Dalton Transactions
Volume	47
Issue number	36
DOIs	https://doi.org/10.1039/c8dt02933d
State	Published - 2018

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title = "Bisphosphine phenol and phenolate complexes of Mn(i): Manganese(i) catalyzed Tishchenko reaction",

abstract = "We synthesized new organomanganese complexes using the phenolic {"}pincer{"} type ligand H-POP. The coordination chemistry of H-POP with Mn(i) was explored, revealing a wide range of binding motifs. Finally, we found that complex 1 catalyzes the formation of benzyl benzoate from benzaldehyde in a Tishchenko reaction.",

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year = "2018",

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T1 - Bisphosphine phenol and phenolate complexes of Mn(i)

T2 - Manganese(i) catalyzed Tishchenko reaction

AU - Kadassery, Karthika J.

AU - MacMillan, Samantha N.

AU - Lacy, David C.

PY - 2018

Y1 - 2018

N2 - We synthesized new organomanganese complexes using the phenolic "pincer" type ligand H-POP. The coordination chemistry of H-POP with Mn(i) was explored, revealing a wide range of binding motifs. Finally, we found that complex 1 catalyzes the formation of benzyl benzoate from benzaldehyde in a Tishchenko reaction.

AB - We synthesized new organomanganese complexes using the phenolic "pincer" type ligand H-POP. The coordination chemistry of H-POP with Mn(i) was explored, revealing a wide range of binding motifs. Finally, we found that complex 1 catalyzes the formation of benzyl benzoate from benzaldehyde in a Tishchenko reaction.

UR - https://www.scopus.com/pages/publications/85053694134

U2 - 10.1039/c8dt02933d

DO - 10.1039/c8dt02933d

M3 - Article

SN - 1477-9226

VL - 47

SP - 12652

EP - 12655

JO - Dalton Transactions

JF - Dalton Transactions

IS - 36

ER -

Bisphosphine phenol and phenolate complexes of Mn(i): Manganese(i) catalyzed Tishchenko reaction

Abstract

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