Boron-hyperdoped silicon for the selective oxidative dehydrogenation of propane to propylene

Junjie Chen; Parham Rohani; Stavros G. Karakalos; Michael J. Lance; Todd J. Toops; Mark T. Swihart; Eleni A. Kyriakidou

doi:10.1039/d0cc02822c

Boron-hyperdoped silicon for the selective oxidative dehydrogenation of propane to propylene

Junjie Chen
, Parham Rohani
, Stavros G. Karakalos
, Michael J. Lance
, Todd J. Toops
, Mark T. Swihart
, Eleni A. Kyriakidou

Department of Chemical and Biological Engineering

University at Buffalo

SUNY Buffalo
University of South Carolina
Oak Ridge National Laboratory

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

Boron containing catalysts have great potential in the oxidative dehydrogenation of propane. Herein, a series of 15, 25 and 42 at% boron-hyperdoped silicon catalysts synthesized by laser pyrolysis was studied. Boron-hyperdoped silicon samples showed >6 times higher propylene productivity than commercial h-BN at 450 °C.

Original language	English
Pages (from-to)	9882-9885
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	68
DOIs	https://doi.org/10.1039/d0cc02822c
State	Published - Sep 4 2020

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title = "Boron-hyperdoped silicon for the selective oxidative dehydrogenation of propane to propylene",

abstract = "Boron containing catalysts have great potential in the oxidative dehydrogenation of propane. Herein, a series of 15, 25 and 42 at\% boron-hyperdoped silicon catalysts synthesized by laser pyrolysis was studied. Boron-hyperdoped silicon samples showed >6 times higher propylene productivity than commercial h-BN at 450 °C.",

author = "Junjie Chen and Parham Rohani and Karakalos, \{Stavros G.\} and Lance, \{Michael J.\} and Toops, \{Todd J.\} and Swihart, \{Mark T.\} and Kyriakidou, \{Eleni A.\}",

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doi = "10.1039/d0cc02822c",

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T1 - Boron-hyperdoped silicon for the selective oxidative dehydrogenation of propane to propylene

AU - Chen, Junjie

AU - Rohani, Parham

AU - Karakalos, Stavros G.

AU - Lance, Michael J.

AU - Toops, Todd J.

AU - Swihart, Mark T.

AU - Kyriakidou, Eleni A.

PY - 2020/9/4

Y1 - 2020/9/4

N2 - Boron containing catalysts have great potential in the oxidative dehydrogenation of propane. Herein, a series of 15, 25 and 42 at% boron-hyperdoped silicon catalysts synthesized by laser pyrolysis was studied. Boron-hyperdoped silicon samples showed >6 times higher propylene productivity than commercial h-BN at 450 °C.

AB - Boron containing catalysts have great potential in the oxidative dehydrogenation of propane. Herein, a series of 15, 25 and 42 at% boron-hyperdoped silicon catalysts synthesized by laser pyrolysis was studied. Boron-hyperdoped silicon samples showed >6 times higher propylene productivity than commercial h-BN at 450 °C.

UR - https://www.scopus.com/pages/publications/85090075339

U2 - 10.1039/d0cc02822c

DO - 10.1039/d0cc02822c

M3 - Article

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SN - 1359-7345

VL - 56

SP - 9882

EP - 9885

JO - Chemical Communications

JF - Chemical Communications

IS - 68

ER -

Boron-hyperdoped silicon for the selective oxidative dehydrogenation of propane to propylene

Abstract

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