Chemical reactivity of [(NO)n(ROH)m]+ cluster ions

Jay P. Charlebois; Robert L. DeLeon; James F. Garvey

doi:10.1021/jp001594v

Chemical reactivity of [(NO)_n(ROH)_m]⁺ cluster ions

Jay P. Charlebois
, Robert L. DeLeon
, James F. Garvey

University at Buffalo

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Mixed clusters of nitric oxide and various alcohols (ethanol, n-propanol, 2-propanol, n-butanol, 2-butanol, and tert-butyl alcohol) were generated via a continuous molecular beam expansion and analyzed using an electron impact tandem triple quadrupole mass spectrometer. The unique chemistry of the [(NO)_n(ROH)_m]⁺ cluster ions was investigated employing collision induced dissociation (CID). Formation of product cluster ions containing alkyl nitrites [(NO)_n(RONO)]⁺ and the subsequent loss of neutral HNO (when n = 1) are the most prominent features of this chemistry.

Original language	English
Pages (from-to)	6799-6803
Number of pages	5
Journal	Journal of Physical Chemistry A
Volume	104
Issue number	29
DOIs	https://doi.org/10.1021/jp001594v
State	Published - Jul 27 2000

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@article{994ffed08718427295d762ff996e9032,

title = "Chemical reactivity of [(NO)n(ROH)m]+ cluster ions",

abstract = "Mixed clusters of nitric oxide and various alcohols (ethanol, n-propanol, 2-propanol, n-butanol, 2-butanol, and tert-butyl alcohol) were generated via a continuous molecular beam expansion and analyzed using an electron impact tandem triple quadrupole mass spectrometer. The unique chemistry of the [(NO)n(ROH)m]+ cluster ions was investigated employing collision induced dissociation (CID). Formation of product cluster ions containing alkyl nitrites [(NO)n(RONO)]+ and the subsequent loss of neutral HNO (when n = 1) are the most prominent features of this chemistry.",

author = "Charlebois, \{Jay P.\} and DeLeon, \{Robert L.\} and Garvey, \{James F.\}",

year = "2000",

month = jul,

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doi = "10.1021/jp001594v",

language = "English",

volume = "104",

pages = "6799--6803",

journal = "Journal of Physical Chemistry A",

issn = "1089-5639",

publisher = "American Chemical Society",

number = "29",

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TY - JOUR

T1 - Chemical reactivity of [(NO)n(ROH)m]+ cluster ions

AU - Charlebois, Jay P.

AU - DeLeon, Robert L.

AU - Garvey, James F.

PY - 2000/7/27

Y1 - 2000/7/27

N2 - Mixed clusters of nitric oxide and various alcohols (ethanol, n-propanol, 2-propanol, n-butanol, 2-butanol, and tert-butyl alcohol) were generated via a continuous molecular beam expansion and analyzed using an electron impact tandem triple quadrupole mass spectrometer. The unique chemistry of the [(NO)n(ROH)m]+ cluster ions was investigated employing collision induced dissociation (CID). Formation of product cluster ions containing alkyl nitrites [(NO)n(RONO)]+ and the subsequent loss of neutral HNO (when n = 1) are the most prominent features of this chemistry.

AB - Mixed clusters of nitric oxide and various alcohols (ethanol, n-propanol, 2-propanol, n-butanol, 2-butanol, and tert-butyl alcohol) were generated via a continuous molecular beam expansion and analyzed using an electron impact tandem triple quadrupole mass spectrometer. The unique chemistry of the [(NO)n(ROH)m]+ cluster ions was investigated employing collision induced dissociation (CID). Formation of product cluster ions containing alkyl nitrites [(NO)n(RONO)]+ and the subsequent loss of neutral HNO (when n = 1) are the most prominent features of this chemistry.

UR - https://www.scopus.com/pages/publications/0034224330

U2 - 10.1021/jp001594v

DO - 10.1021/jp001594v

M3 - Article

SN - 1089-5639

VL - 104

SP - 6799

EP - 6803

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 29

ER -

Chemical reactivity of [(NO)_n(ROH)_m]⁺ cluster ions

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