Coordinated and clathrated molecular diiodine in [Rh2(O2CCF3)4I2]·I2

F. Albert Cotton; Evgeny V. Dikarev; Marina A. Petrukhina

doi:10.1002/1521-3773(20000703)39:13

Coordinated and clathrated molecular diiodine in [Rh₂(O₂CCF₃)₄I₂]·I₂

Chemistry

University at Albany

Texas A&M University

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

A bidentate bridging coordination of molecular diiodine has been found for the first time in [Rh₂-(O₂CCF₃)₄I₂]·I₂, which was obtained by deposition from the vapor phase. An X-ray structure reveals a zigzag chain polymer (shown in the picture) formed by alternating [Rh₂(O₂CCF₃)₄] and I₂ molecules; another diiodine molecule is clathrated within the channels of the network.

Original language	English
Pages (from-to)	2362-2364
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	13
DOIs	https://doi.org/10.1002/1521-3773(20000703)39:13
State	Published - Jul 3 2000

Keywords

Carboxylato complexes
Clathrates
Coordination modes
Iodine
Rhodium

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10.1002/1521-3773(20000703)39:13

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title = "Coordinated and clathrated molecular diiodine in [Rh2(O2CCF3)4I2]·I2",

abstract = "A bidentate bridging coordination of molecular diiodine has been found for the first time in [Rh2-(O2CCF3)4I2]·I2, which was obtained by deposition from the vapor phase. An X-ray structure reveals a zigzag chain polymer (shown in the picture) formed by alternating [Rh2(O2CCF3)4] and I2 molecules; another diiodine molecule is clathrated within the channels of the network.",

keywords = "Carboxylato complexes, Clathrates, Coordination modes, Iodine, Rhodium",

author = "Cotton, \{F. Albert\} and Dikarev, \{Evgeny V.\} and Petrukhina, \{Marina A.\}",

year = "2000",

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doi = "10.1002/1521-3773(20000703)39:13",

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T1 - Coordinated and clathrated molecular diiodine in [Rh2(O2CCF3)4I2]·I2

AU - Cotton, F. Albert

AU - Dikarev, Evgeny V.

AU - Petrukhina, Marina A.

PY - 2000/7/3

Y1 - 2000/7/3

N2 - A bidentate bridging coordination of molecular diiodine has been found for the first time in [Rh2-(O2CCF3)4I2]·I2, which was obtained by deposition from the vapor phase. An X-ray structure reveals a zigzag chain polymer (shown in the picture) formed by alternating [Rh2(O2CCF3)4] and I2 molecules; another diiodine molecule is clathrated within the channels of the network.

AB - A bidentate bridging coordination of molecular diiodine has been found for the first time in [Rh2-(O2CCF3)4I2]·I2, which was obtained by deposition from the vapor phase. An X-ray structure reveals a zigzag chain polymer (shown in the picture) formed by alternating [Rh2(O2CCF3)4] and I2 molecules; another diiodine molecule is clathrated within the channels of the network.

KW - Carboxylato complexes

KW - Clathrates

KW - Coordination modes

KW - Iodine

KW - Rhodium

UR - https://www.scopus.com/pages/publications/0034600908

U2 - 10.1002/1521-3773(20000703)39:13

DO - 10.1002/1521-3773(20000703)39:13

M3 - Article

SN - 1433-7851

VL - 39

SP - 2362

EP - 2364

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13

ER -

Coordinated and clathrated molecular diiodine in [Rh₂(O₂CCF₃)₄I₂]·I₂

Abstract

Keywords

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