Copper(I) butyrate: A tetranuclear core revealed

Oleksandr Hietsoi; Alexander S. Filatov; Marina A. Petrukhina

doi:10.1524/zkri.2012.1435

Copper(I) butyrate: A tetranuclear core revealed

Oleksandr Hietsoi
, Alexander S. Filatov
, Marina A. Petrukhina

Chemistry

University at Albany

SUNY Albany

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title complex, [Cu ₄(O ₂CCH ₂CH ₂CH ₃) ₄] (1), has a planar core comprised of four copper atoms bridged by four butyrate ligands alternating above and below the Cu ₄-plane. The intramolecular Cu · · · Cu distances within the Cu ₄-core are very close, being 2.7255(5) and 2.7261(5) Å. In the solid-state, the Cu ₄-units are engaged in additional intermolecular copper-oxygen interactions to form a 1D polymeric structure with average Cu · · · O contacts of ca. 2.427(2) Å.

Original language	English
Pages (from-to)	147-150
Number of pages	4
Journal	Zeitschrift fur Kristallographie
Volume	227
Issue number	3
DOIs	https://doi.org/10.1524/zkri.2012.1435
State	Published - Mar 2012

Keywords

Copper(I) butyrate
Photoluminescence
Single crystal structure analysis
X-ray diffraction

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@article{c9f7af77208e4642908cf605248ef6b9,

title = "Copper(I) butyrate: A tetranuclear core revealed",

abstract = "The title complex, [Cu 4(O 2CCH 2CH 2CH 3) 4] (1), has a planar core comprised of four copper atoms bridged by four butyrate ligands alternating above and below the Cu 4-plane. The intramolecular Cu · · · Cu distances within the Cu 4-core are very close, being 2.7255(5) and 2.7261(5) {\AA}. In the solid-state, the Cu 4-units are engaged in additional intermolecular copper-oxygen interactions to form a 1D polymeric structure with average Cu · · · O contacts of ca. 2.427(2) {\AA}.",

keywords = "Copper(I) butyrate, Photoluminescence, Single crystal structure analysis, X-ray diffraction",

author = "Oleksandr Hietsoi and Filatov, \{Alexander S.\} and Petrukhina, \{Marina A.\}",

year = "2012",

month = mar,

doi = "10.1524/zkri.2012.1435",

language = "English",

volume = "227",

pages = "147--150",

journal = "Zeitschrift fur Kristallographie",

issn = "0044-2968",

number = "3",

}

TY - JOUR

T1 - Copper(I) butyrate

T2 - A tetranuclear core revealed

AU - Hietsoi, Oleksandr

AU - Filatov, Alexander S.

AU - Petrukhina, Marina A.

PY - 2012/3

Y1 - 2012/3

N2 - The title complex, [Cu 4(O 2CCH 2CH 2CH 3) 4] (1), has a planar core comprised of four copper atoms bridged by four butyrate ligands alternating above and below the Cu 4-plane. The intramolecular Cu · · · Cu distances within the Cu 4-core are very close, being 2.7255(5) and 2.7261(5) Å. In the solid-state, the Cu 4-units are engaged in additional intermolecular copper-oxygen interactions to form a 1D polymeric structure with average Cu · · · O contacts of ca. 2.427(2) Å.

AB - The title complex, [Cu 4(O 2CCH 2CH 2CH 3) 4] (1), has a planar core comprised of four copper atoms bridged by four butyrate ligands alternating above and below the Cu 4-plane. The intramolecular Cu · · · Cu distances within the Cu 4-core are very close, being 2.7255(5) and 2.7261(5) Å. In the solid-state, the Cu 4-units are engaged in additional intermolecular copper-oxygen interactions to form a 1D polymeric structure with average Cu · · · O contacts of ca. 2.427(2) Å.

KW - Copper(I) butyrate

KW - Photoluminescence

KW - Single crystal structure analysis

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/84865011377

U2 - 10.1524/zkri.2012.1435

DO - 10.1524/zkri.2012.1435

M3 - Article

SN - 0044-2968

VL - 227

SP - 147

EP - 150

JO - Zeitschrift fur Kristallographie

JF - Zeitschrift fur Kristallographie

IS - 3

ER -

Copper(I) butyrate: A tetranuclear core revealed

Abstract

Keywords

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