Crystal Structure of SbSeBr and BiSeI from X-ray Powder Diffraction

V. A. Trifonov; A. V. SheveL'Kov; E. V. Dikarev; B. A. Popovkin

Crystal Structure of SbSeBr and BiSeI from X-ray Powder Diffraction

V. A. Trifonov
, A. V. SheveL'Kov
, E. V. Dikarev
, B. A. Popovkin

Chemistry

University at Albany

Lomonosov Moscow State University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Selenide halides SbSeBr (I) and BiSeI (II) are prepared by the ampule method. The crystal structures of the phases are determined based on X-ray powder diffraction data with the Rietveld full-profile method. The crystals are orthorhombic, space group Pnam. The unit cell parameters for I: a = 8.3201(3) Å, b = 10.2313(4) Å, c = 4.0163(1) Å, Z = 4; for II: a = 8.7035(2) Å, b = 10.5796(2) Å, c = 4.21879(6) Å, Z = 4. In both structures, which are related to the SbSBr structural type, double strips constituted by metal and selenium atoms and bonded together by halogen atoms may be distinguished.

Original language	English
Pages (from-to)	5-8
Number of pages	4
Journal	Russian Journal of Inorganic Chemistry
Volume	44
Issue number	1
State	Published - Jan 1999

Cite this

@article{afff0afe266f48a987ea05f3112a27c9,

title = "Crystal Structure of SbSeBr and BiSeI from X-ray Powder Diffraction",

abstract = "Selenide halides SbSeBr (I) and BiSeI (II) are prepared by the ampule method. The crystal structures of the phases are determined based on X-ray powder diffraction data with the Rietveld full-profile method. The crystals are orthorhombic, space group Pnam. The unit cell parameters for I: a = 8.3201(3) {\AA}, b = 10.2313(4) {\AA}, c = 4.0163(1) {\AA}, Z = 4; for II: a = 8.7035(2) {\AA}, b = 10.5796(2) {\AA}, c = 4.21879(6) {\AA}, Z = 4. In both structures, which are related to the SbSBr structural type, double strips constituted by metal and selenium atoms and bonded together by halogen atoms may be distinguished.",

author = "Trifonov, \{V. A.\} and SheveL'Kov, \{A. V.\} and Dikarev, \{E. V.\} and Popovkin, \{B. A.\}",

year = "1999",

month = jan,

language = "English",

volume = "44",

pages = "5--8",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Pleiades Publishing",

number = "1",

}

TY - JOUR

T1 - Crystal Structure of SbSeBr and BiSeI from X-ray Powder Diffraction

AU - Trifonov, V. A.

AU - SheveL'Kov, A. V.

AU - Dikarev, E. V.

AU - Popovkin, B. A.

PY - 1999/1

Y1 - 1999/1

N2 - Selenide halides SbSeBr (I) and BiSeI (II) are prepared by the ampule method. The crystal structures of the phases are determined based on X-ray powder diffraction data with the Rietveld full-profile method. The crystals are orthorhombic, space group Pnam. The unit cell parameters for I: a = 8.3201(3) Å, b = 10.2313(4) Å, c = 4.0163(1) Å, Z = 4; for II: a = 8.7035(2) Å, b = 10.5796(2) Å, c = 4.21879(6) Å, Z = 4. In both structures, which are related to the SbSBr structural type, double strips constituted by metal and selenium atoms and bonded together by halogen atoms may be distinguished.

AB - Selenide halides SbSeBr (I) and BiSeI (II) are prepared by the ampule method. The crystal structures of the phases are determined based on X-ray powder diffraction data with the Rietveld full-profile method. The crystals are orthorhombic, space group Pnam. The unit cell parameters for I: a = 8.3201(3) Å, b = 10.2313(4) Å, c = 4.0163(1) Å, Z = 4; for II: a = 8.7035(2) Å, b = 10.5796(2) Å, c = 4.21879(6) Å, Z = 4. In both structures, which are related to the SbSBr structural type, double strips constituted by metal and selenium atoms and bonded together by halogen atoms may be distinguished.

UR - https://www.scopus.com/pages/publications/0007201925

M3 - Article

SN - 0036-0236

VL - 44

SP - 5

EP - 8

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 1

ER -

Crystal Structure of SbSeBr and BiSeI from X-ray Powder Diffraction

Abstract

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