Crystal structure of the methanol solvate of (η5-cyclopentadienyl)[1,2-bis(diphenylphosphino)ethane] nitroruthenium(II), Ru(η5-C5H5)(dppe)(NO2)·CH 3OH

Melvyn Rowen Churchill; Charles H. Lake; Lisa F. Szczepura; Kenneth J. Takeuchi

doi:10.1007/BF01668310

Crystal structure of the methanol solvate of (η5-cyclopentadienyl)[1,2-bis(diphenylphosphino)ethane] nitroruthenium(II), Ru(η5-C₅H₅)(dppe)(NO₂)·CH ₃OH

Melvyn Rowen Churchill
, Charles H. Lake
, Lisa F. Szczepura
, Kenneth J. Takeuchi

Chemistry

Stony Brook University

SUNY Buffalo
University of Alabama at Birmingham
University of Illinois at Urbana-Champaign

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The title complex crystallizes in the centrosymmetric monoclinic space group C2/c (No. 15) with Z = 8. The structure was refined to R = 4.49% for those 2745 independent reflections with 2θ = 5-50° and |F_σ| > 6σ(F). Ruthenium-ligand distances are as follows: Ru-P = 2.284(2) and 2.286(2) Å, Ru-NO₂ = 2.049(6) Å and Ru-C(Cp) = 2.210(10)-2.246(9) Å. Bond lengths within the nitro ligand are N(1)-O(1) = 1.226(10) Å and N(1)-O(2) = 1.244(10) Å. The methanol of solvation is ordered but is subject to large thermal vibrational motions.

Original language	English
Pages (from-to)	489-495
Number of pages	7
Journal	Journal of Chemical Crystallography
Volume	26
Issue number	7
DOIs	https://doi.org/10.1007/BF01668310
State	Published - Jul 1996

Keywords

Bis(1,2-diphenylphosphino)ethane ligand
Crystal structure
Cyclopentadienyl derivative
Methanol solvate
Organoruthenium compound
Ruthenium(ii) complex
Ruthenium-nitro complex

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10.1007/BF01668310

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@article{9b7d72a1c05841f4ba5988218307fb29,

title = "Crystal structure of the methanol solvate of (η5-cyclopentadienyl)[1,2-bis(diphenylphosphino)ethane] nitroruthenium(II), Ru(η5-C5H5)(dppe)(NO2)·CH 3OH",

abstract = "The title complex crystallizes in the centrosymmetric monoclinic space group C2/c (No. 15) with Z = 8. The structure was refined to R = 4.49\% for those 2745 independent reflections with 2θ = 5-50° and |Fσ| > 6σ(F). Ruthenium-ligand distances are as follows: Ru-P = 2.284(2) and 2.286(2) {\AA}, Ru-NO2 = 2.049(6) {\AA} and Ru-C(Cp) = 2.210(10)-2.246(9) {\AA}. Bond lengths within the nitro ligand are N(1)-O(1) = 1.226(10) {\AA} and N(1)-O(2) = 1.244(10) {\AA}. The methanol of solvation is ordered but is subject to large thermal vibrational motions.",

keywords = "Bis(1,2-diphenylphosphino)ethane ligand, Crystal structure, Cyclopentadienyl derivative, Methanol solvate, Organoruthenium compound, Ruthenium(ii) complex, Ruthenium-nitro complex",

author = "Churchill, \{Melvyn Rowen\} and Lake, \{Charles H.\} and Szczepura, \{Lisa F.\} and Takeuchi, \{Kenneth J.\}",

year = "1996",

month = jul,

doi = "10.1007/BF01668310",

language = "English",

volume = "26",

pages = "489--495",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

publisher = "Springer",

number = "7",

}

Crystal structure of the methanol solvate of (η5-cyclopentadienyl)[1,2-bis(diphenylphosphino)ethane] nitroruthenium(II), Ru(η5-C₅H₅)(dppe)(NO₂)·CH ₃OH. / Churchill, Melvyn Rowen; Lake, Charles H.; Szczepura, Lisa F. et al.
In: Journal of Chemical Crystallography, Vol. 26, No. 7, 07.1996, p. 489-495.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal structure of the methanol solvate of (η5-cyclopentadienyl)[1,2-bis(diphenylphosphino)ethane] nitroruthenium(II), Ru(η5-C5H5)(dppe)(NO2)·CH 3OH

AU - Churchill, Melvyn Rowen

AU - Lake, Charles H.

AU - Szczepura, Lisa F.

AU - Takeuchi, Kenneth J.

PY - 1996/7

Y1 - 1996/7

N2 - The title complex crystallizes in the centrosymmetric monoclinic space group C2/c (No. 15) with Z = 8. The structure was refined to R = 4.49% for those 2745 independent reflections with 2θ = 5-50° and |Fσ| > 6σ(F). Ruthenium-ligand distances are as follows: Ru-P = 2.284(2) and 2.286(2) Å, Ru-NO2 = 2.049(6) Å and Ru-C(Cp) = 2.210(10)-2.246(9) Å. Bond lengths within the nitro ligand are N(1)-O(1) = 1.226(10) Å and N(1)-O(2) = 1.244(10) Å. The methanol of solvation is ordered but is subject to large thermal vibrational motions.

AB - The title complex crystallizes in the centrosymmetric monoclinic space group C2/c (No. 15) with Z = 8. The structure was refined to R = 4.49% for those 2745 independent reflections with 2θ = 5-50° and |Fσ| > 6σ(F). Ruthenium-ligand distances are as follows: Ru-P = 2.284(2) and 2.286(2) Å, Ru-NO2 = 2.049(6) Å and Ru-C(Cp) = 2.210(10)-2.246(9) Å. Bond lengths within the nitro ligand are N(1)-O(1) = 1.226(10) Å and N(1)-O(2) = 1.244(10) Å. The methanol of solvation is ordered but is subject to large thermal vibrational motions.

KW - Bis(1,2-diphenylphosphino)ethane ligand

KW - Crystal structure

KW - Cyclopentadienyl derivative

KW - Methanol solvate

KW - Organoruthenium compound

KW - Ruthenium(ii) complex

KW - Ruthenium-nitro complex

UR - https://www.scopus.com/pages/publications/0040834511

U2 - 10.1007/BF01668310

DO - 10.1007/BF01668310

M3 - Article

SN - 1074-1542

VL - 26

SP - 489

EP - 495

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 7

ER -

Crystal structure of the methanol solvate of (η5-cyclopentadienyl)[1,2-bis(diphenylphosphino)ethane] nitroruthenium(II), Ru(η5-C₅H₅)(dppe)(NO₂)·CH ₃OH

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