Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker

Anna M. Plonka; Debasis Banerjee; William R. Woerner; Zhijuan Zhang; Jing Li; John B. Parise

doi:10.1039/c3cc43299h

Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker

Anna M. Plonka
, Debasis Banerjee
, William R. Woerner
, Zhijuan Zhang
, Jing Li
, John B. Parise

Geosciences

Stony Brook University

Stony Brook University
Rutgers - The State University of New Jersey, New Brunswick

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO₂ over N₂. The selectivity is attributed to CO₂ interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.

Original language	English
Pages (from-to)	7055-7057
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	63
DOIs	https://doi.org/10.1039/c3cc43299h
State	Published - Jul 11 2013

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title = "Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker",

abstract = "A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.",

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T2 - The case of a microporous cadmium metal organic framework with a V-shaped linker

AU - Plonka, Anna M.

AU - Banerjee, Debasis

AU - Woerner, William R.

AU - Zhang, Zhijuan

AU - Li, Jing

AU - Parise, John B.

PY - 2013/7/11

Y1 - 2013/7/11

N2 - A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.

AB - A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.

UR - https://www.scopus.com/pages/publications/84882282058

U2 - 10.1039/c3cc43299h

DO - 10.1039/c3cc43299h

M3 - Article

SN - 1359-7345

VL - 49

SP - 7055

EP - 7057

JO - Chemical Communications

JF - Chemical Communications

IS - 63

ER -

Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker

Abstract

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