Enhanced basicity of an electron donor-acceptor complex

Bernard G. Stevenson; Amanada V. Prascsak; Annemarie A. Lee; Eric D. Talbott; Lisa A. Fredin; John R. Swierk

doi:10.1039/d2cc05985a

Enhanced basicity of an electron donor-acceptor complex

Bernard G. Stevenson
, Amanada V. Prascsak
, Annemarie A. Lee
, Eric D. Talbott
, Lisa A. Fredin
, John R. Swierk

Chemistry

Binghamton University

State University of New York Binghamton University
Lehigh University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

An electron donor-acceptor (EDA) complex forms between 1,4-dicyanobenzene and N-phenylpyrrolidine, which are coupling partners for the α-aminoarylation photoredox reaction. Calculations and experiments demonstrate the EDA complex is a better base than N-phenylpyrroline. A re-analysis of the α-aminoarylation reaction suggests that the EDA complex is a proton acceptor in the reaction.

Original language	English
Pages (from-to)	2943-2945
Number of pages	3
Journal	Chemical Communications
Volume	59
Issue number	20
DOIs	https://doi.org/10.1039/d2cc05985a
State	Published - Feb 13 2023

Access to Document

10.1039/d2cc05985a

Cite this

@article{2154b4ee7ae742e59b9bae5a2b27026f,

title = "Enhanced basicity of an electron donor-acceptor complex",

abstract = "An electron donor-acceptor (EDA) complex forms between 1,4-dicyanobenzene and N-phenylpyrrolidine, which are coupling partners for the α-aminoarylation photoredox reaction. Calculations and experiments demonstrate the EDA complex is a better base than N-phenylpyrroline. A re-analysis of the α-aminoarylation reaction suggests that the EDA complex is a proton acceptor in the reaction.",

author = "Stevenson, \{Bernard G.\} and Prascsak, \{Amanada V.\} and Lee, \{Annemarie A.\} and Talbott, \{Eric D.\} and Fredin, \{Lisa A.\} and Swierk, \{John R.\}",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

month = feb,

day = "13",

doi = "10.1039/d2cc05985a",

language = "English",

volume = "59",

pages = "2943--2945",

journal = "Chemical Communications",

issn = "1359-7345",

number = "20",

}

TY - JOUR

T1 - Enhanced basicity of an electron donor-acceptor complex

AU - Stevenson, Bernard G.

AU - Prascsak, Amanada V.

AU - Lee, Annemarie A.

AU - Talbott, Eric D.

AU - Fredin, Lisa A.

AU - Swierk, John R.

PY - 2023/2/13

Y1 - 2023/2/13

N2 - An electron donor-acceptor (EDA) complex forms between 1,4-dicyanobenzene and N-phenylpyrrolidine, which are coupling partners for the α-aminoarylation photoredox reaction. Calculations and experiments demonstrate the EDA complex is a better base than N-phenylpyrroline. A re-analysis of the α-aminoarylation reaction suggests that the EDA complex is a proton acceptor in the reaction.

AB - An electron donor-acceptor (EDA) complex forms between 1,4-dicyanobenzene and N-phenylpyrrolidine, which are coupling partners for the α-aminoarylation photoredox reaction. Calculations and experiments demonstrate the EDA complex is a better base than N-phenylpyrroline. A re-analysis of the α-aminoarylation reaction suggests that the EDA complex is a proton acceptor in the reaction.

UR - https://www.scopus.com/pages/publications/85148995735

U2 - 10.1039/d2cc05985a

DO - 10.1039/d2cc05985a

M3 - Article

C2 - 36799450

SN - 1359-7345

VL - 59

SP - 2943

EP - 2945

JO - Chemical Communications

JF - Chemical Communications

IS - 20

ER -

Enhanced basicity of an electron donor-acceptor complex

Abstract

Access to Document

Other files and links

Fingerprint

Cite this