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Enhancing by weakening: Electrooxidation of methanol on Pt3Co and Pt nanocubes

  • Hongzhou Yang
  • , Jun Zhang
  • , Kai Sun
  • , Shouzhong Zou
  • , Jiye Fang
  • Miami University
  • State University of New York Binghamton University
  • University of Michigan, Ann Arbor

Research output: Contribution to journalArticlepeer-review

192 Scopus citations

Abstract

(Figure Presented) Loaded dice: High-quality and similarly sized Pt 3Co and Pt nanocubes were prepared by gradually reducing metal precursors at high temperatures. Cyclic voltammetric and chronoamperometric results show a much higher methanol oxidation current density on Pt 3Co nanocubes (see picture). The enhanced catalytic activity was explained by the slower and weaker adsorption of CO onto Pt3Co.

Original languageEnglish
Pages (from-to)6848-6851
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number38
DOIs
StatePublished - Sep 10 2010

Keywords

  • Electrocatalysis
  • Fuel cells
  • Methanol oxidation
  • Nanocubes
  • Platinum

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