Experimental verification of the model of slow structural transformations in lead underpotential adsorbate on Ag(111) faces at low coverages

N. Dimitrov; A. Popov; D. Kashchiev; T. Vitanov; E. Budevski

doi:10.1016/0013-4686(91)80004-R

Experimental verification of the model of slow structural transformations in lead underpotential adsorbate on Ag(111) faces at low coverages

N. Dimitrov
, A. Popov
, D. Kashchiev
, T. Vitanov
, E. Budevski

Chemistry

Binghamton University

Bulgarian Academy of Sciences

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The applicability of a previously proposed model of slow structural transformations in underpotentially adsorbed lead monolayers on Ag(111) faces is investigated at various coverages. The model as a first approximation is found to be applicable for coverages up to 20%. The possible reasons for the inapplicability of the model at higher coverages are discussed.

Original language	English
Pages (from-to)	1259-1262
Number of pages	4
Journal	Electrochimica Acta
Volume	36
Issue number	8
DOIs	https://doi.org/10.1016/0013-4686(91)80004-R
State	Published - 1991

Keywords

UPD
adsorption transformation
monocrystals
silver

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10.1016/0013-4686(91)80004-R

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title = "Experimental verification of the model of slow structural transformations in lead underpotential adsorbate on Ag(111) faces at low coverages",

abstract = "The applicability of a previously proposed model of slow structural transformations in underpotentially adsorbed lead monolayers on Ag(111) faces is investigated at various coverages. The model as a first approximation is found to be applicable for coverages up to 20\%. The possible reasons for the inapplicability of the model at higher coverages are discussed.",

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AU - Dimitrov, N.

AU - Popov, A.

AU - Kashchiev, D.

AU - Vitanov, T.

AU - Budevski, E.

PY - 1991

Y1 - 1991

N2 - The applicability of a previously proposed model of slow structural transformations in underpotentially adsorbed lead monolayers on Ag(111) faces is investigated at various coverages. The model as a first approximation is found to be applicable for coverages up to 20%. The possible reasons for the inapplicability of the model at higher coverages are discussed.

AB - The applicability of a previously proposed model of slow structural transformations in underpotentially adsorbed lead monolayers on Ag(111) faces is investigated at various coverages. The model as a first approximation is found to be applicable for coverages up to 20%. The possible reasons for the inapplicability of the model at higher coverages are discussed.

KW - UPD

KW - adsorption transformation

KW - monocrystals

KW - silver

UR - https://www.scopus.com/pages/publications/30244533921

U2 - 10.1016/0013-4686(91)80004-R

DO - 10.1016/0013-4686(91)80004-R

M3 - Article

SN - 0013-4686

VL - 36

SP - 1259

EP - 1262

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 8

ER -

Experimental verification of the model of slow structural transformations in lead underpotential adsorbate on Ag(111) faces at low coverages

Abstract

Keywords

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