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Fifth to eleventh virial coefficients of hard spheres

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Abstract

Virial coefficients Bn of three-dimensional hard spheres are reported for n=5 to 11, with precision exceeding that presently available in the literature. Calculations are performed using the recursive method due to Wheatley, and a binning approach is proposed to allow more flexibility in where computational effort is directed in the calculations. We highlight the difficulty as a general measure that quantifies performance of an algorithm that computes a stochastic average and show how it can be used as the basis for optimizing such calculations.

Original languageEnglish
Article number023301
JournalPhysical Review E - Statistical, Nonlinear, and Soft Matter Physics
Volume90
Issue number2
DOIs
StatePublished - Aug 4 2014

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