From a bismuth oxido diketonate to a giant bismuth oxido cluster

Evgeny V. Dikarev; Haitao Zhang; Bo Li

doi:10.1002/anie.200601675

From a bismuth oxido diketonate to a giant bismuth oxido cluster

Evgeny V. Dikarev
, Haitao Zhang
, Bo Li

Chemistry

University at Albany

SUNY Albany

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Aggregation in coordinating solvents: A giant oxido cluster [Bi ₃₈O₄₅(hfac)₂₄] (hfac = hexafluoroacetylacetonate), formed in solutions of bismuth oxido diketonate [Bi₉O₇(hfac)₁₃], has been isolated and fully characterized. The [Bi₃₈O₄₅]²⁴⁺ core (see picture: orange Bi, red O; central Bi₆O₉ unit is highlighted) is capped by 24 hfac ligands, has a size larger than 2 nm, and may serve as a model for investigating the chemistry of bismuth oxide nanoparticles. (Figure Presented).

Original language	English
Pages (from-to)	5448-5451
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	33
DOIs	https://doi.org/10.1002/anie.200601675
State	Published - Aug 18 2006

Keywords

Bismuth
Cluster compounds
O ligands
Oxido ligands

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title = "From a bismuth oxido diketonate to a giant bismuth oxido cluster",

abstract = "Aggregation in coordinating solvents: A giant oxido cluster [Bi 38O45(hfac)24] (hfac = hexafluoroacetylacetonate), formed in solutions of bismuth oxido diketonate [Bi9O7(hfac)13], has been isolated and fully characterized. The [Bi38O45]24+ core (see picture: orange Bi, red O; central Bi6O9 unit is highlighted) is capped by 24 hfac ligands, has a size larger than 2 nm, and may serve as a model for investigating the chemistry of bismuth oxide nanoparticles. (Figure Presented).",

keywords = "Bismuth, Cluster compounds, O ligands, Oxido ligands",

author = "Dikarev, \{Evgeny V.\} and Haitao Zhang and Bo Li",

year = "2006",

month = aug,

day = "18",

doi = "10.1002/anie.200601675",

language = "English",

volume = "45",

pages = "5448--5451",

journal = "Angewandte Chemie - International Edition",

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T1 - From a bismuth oxido diketonate to a giant bismuth oxido cluster

AU - Dikarev, Evgeny V.

AU - Zhang, Haitao

AU - Li, Bo

PY - 2006/8/18

Y1 - 2006/8/18

N2 - Aggregation in coordinating solvents: A giant oxido cluster [Bi 38O45(hfac)24] (hfac = hexafluoroacetylacetonate), formed in solutions of bismuth oxido diketonate [Bi9O7(hfac)13], has been isolated and fully characterized. The [Bi38O45]24+ core (see picture: orange Bi, red O; central Bi6O9 unit is highlighted) is capped by 24 hfac ligands, has a size larger than 2 nm, and may serve as a model for investigating the chemistry of bismuth oxide nanoparticles. (Figure Presented).

AB - Aggregation in coordinating solvents: A giant oxido cluster [Bi 38O45(hfac)24] (hfac = hexafluoroacetylacetonate), formed in solutions of bismuth oxido diketonate [Bi9O7(hfac)13], has been isolated and fully characterized. The [Bi38O45]24+ core (see picture: orange Bi, red O; central Bi6O9 unit is highlighted) is capped by 24 hfac ligands, has a size larger than 2 nm, and may serve as a model for investigating the chemistry of bismuth oxide nanoparticles. (Figure Presented).

KW - Bismuth

KW - Cluster compounds

KW - O ligands

KW - Oxido ligands

UR - https://www.scopus.com/pages/publications/33748644918

U2 - 10.1002/anie.200601675

DO - 10.1002/anie.200601675

M3 - Article

SN - 1433-7851

VL - 45

SP - 5448

EP - 5451

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 33

ER -

From a bismuth oxido diketonate to a giant bismuth oxido cluster

Abstract

Keywords

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