Gaseous mercury re-emission from wet flue gas desulfurization wastewater aeration basins: A review

Wet flue gas desulfurization (WFGD) simultaneously removes Hg and SO₂ from coal-fired power plant flue gas streams. Hg⁰ re-emission occurs when the dissolved Hg(II) is converted to a volatile form (i.e., Hg⁰) that can be subsequently emitted into the ambient air from WFGD wastewater aeration basins. Others have shown that Hg⁰ re-emission depends on pH, temperature, ligands (Cl, Br, I, F, SO₃^2-, SO₄^2-, NO₃^-, SCN^-, and ClO^-), O₂, minerals (Se and As), and metals (Fe and Cu) in WFGD wastewater. Still others have shown Hg⁰ re-emission restriction via inhibitor addition (adsorbents and precipitators). This is the first review that summarizes the complex and inconsistently reported Hg⁰ re-emission mechanisms, updates misconceptions related to Hg(II) complexation and reduction, and reviews applications of inhibitors that convert aqueous Hg(II) into stable solid forms to prevent gaseous Hg⁰ formation and release.