Heterobimetallic main-group-transition-metal paddle-wheel carboxylates

Evgeny V. Dikarev; Thomas G. Gray; Bo Li

doi:10.1002/anie.200462433

Heterobimetallic main-group-transition-metal paddle-wheel carboxylates

Evgeny V. Dikarev
, Thomas G. Gray
, Bo Li

Chemistry

University at Albany

Case Western Reserve University
SUNY Albany

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

(Chemical Equation Presented) Bismuth(II) tetra(trifluoroacetate) acts as a metalloligand toward transition-metal units to yield heterobimetallic homoleptic carboxylates [BiM(O₂CCF₃)₄] (M = Rh, Ru; see picture). The heterometallic molecules maintain a paddle-wheel structure, with a single bond between bismuth and the transition-metal atom, and behave as one-ended Lewis acids in solution and in the solid state.

Original language	English
Pages (from-to)	1721-1724
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	11
DOIs	https://doi.org/10.1002/anie.200462433
State	Published - Mar 4 2005

Keywords

Bismuth
Carboxylate ligands
Density functional calculations
Heterometallic complexes
Transition metals

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10.1002/anie.200462433

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title = "Heterobimetallic main-group-transition-metal paddle-wheel carboxylates",

abstract = "(Chemical Equation Presented) Bismuth(II) tetra(trifluoroacetate) acts as a metalloligand toward transition-metal units to yield heterobimetallic homoleptic carboxylates [BiM(O2CCF3)4] (M = Rh, Ru; see picture). The heterometallic molecules maintain a paddle-wheel structure, with a single bond between bismuth and the transition-metal atom, and behave as one-ended Lewis acids in solution and in the solid state.",

keywords = "Bismuth, Carboxylate ligands, Density functional calculations, Heterometallic complexes, Transition metals",

author = "Dikarev, \{Evgeny V.\} and Gray, \{Thomas G.\} and Bo Li",

year = "2005",

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doi = "10.1002/anie.200462433",

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T1 - Heterobimetallic main-group-transition-metal paddle-wheel carboxylates

AU - Dikarev, Evgeny V.

AU - Gray, Thomas G.

AU - Li, Bo

PY - 2005/3/4

Y1 - 2005/3/4

N2 - (Chemical Equation Presented) Bismuth(II) tetra(trifluoroacetate) acts as a metalloligand toward transition-metal units to yield heterobimetallic homoleptic carboxylates [BiM(O2CCF3)4] (M = Rh, Ru; see picture). The heterometallic molecules maintain a paddle-wheel structure, with a single bond between bismuth and the transition-metal atom, and behave as one-ended Lewis acids in solution and in the solid state.

AB - (Chemical Equation Presented) Bismuth(II) tetra(trifluoroacetate) acts as a metalloligand toward transition-metal units to yield heterobimetallic homoleptic carboxylates [BiM(O2CCF3)4] (M = Rh, Ru; see picture). The heterometallic molecules maintain a paddle-wheel structure, with a single bond between bismuth and the transition-metal atom, and behave as one-ended Lewis acids in solution and in the solid state.

KW - Bismuth

KW - Carboxylate ligands

KW - Density functional calculations

KW - Heterometallic complexes

KW - Transition metals

UR - https://www.scopus.com/pages/publications/17044368409

U2 - 10.1002/anie.200462433

DO - 10.1002/anie.200462433

M3 - Article

C2 - 15693042

SN - 1433-7851

VL - 44

SP - 1721

EP - 1724

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 11

ER -

Heterobimetallic main-group-transition-metal paddle-wheel carboxylates

Abstract

Keywords

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