H3PW12O40at the[bmim][FeCl4]: A green catalytic system for alkoxymethylation of alcohols and their one-pot interconversion to acetates and TMS-ethers

I. Mohammadpoor-Baltork; M. Moghadam; S. Tangestaninejad; V. Mirkhani; A. R. Khosropour; A. Mirjafari

doi:10.1007/BF03249085

H₃PW₁₂O₄₀at the[bmim][FeCl₄]: A green catalytic system for alkoxymethylation of alcohols and their one-pot interconversion to acetates and TMS-ethers

I. Mohammadpoor-Baltork
, M. Moghadam
, S. Tangestaninejad
, V. Mirkhani
, A. R. Khosropour
, A. Mirjafari

Chemistry

SUNY Oswego

University of Isfahan

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

12-Tungstophosphoric acid immobilized on [bmim][FeCl₄] was found to be an efficient catalyst for chemoselective methoxymethylation and ethxoymethylation of alcohols and also one-pot conversion of MOM- or EOM-ethers to their corresponding acetates and TMS-ethers under thermal conditions and microwave irradiation. These procedures were simple, rapid and the corresponding products were obtained in high yields. The catalyst exhibited remarkable reactivity and was reusable.

Original language	English
Pages (from-to)	513-524
Number of pages	12
Journal	Journal of the Iranian Chemical Society
Volume	8
Issue number	2
DOIs	https://doi.org/10.1007/BF03249085
State	Published - Jun 2011

Keywords

1-Butyl-methylimidazolium tetrachloroferrate
12-Tungstophosphoric acid
Alkoxymethyl ether
Interconversion
Protection

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10.1007/BF03249085

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title = "H3PW12O40at the[bmim][FeCl4]: A green catalytic system for alkoxymethylation of alcohols and their one-pot interconversion to acetates and TMS-ethers",

abstract = "12-Tungstophosphoric acid immobilized on [bmim][FeCl4] was found to be an efficient catalyst for chemoselective methoxymethylation and ethxoymethylation of alcohols and also one-pot conversion of MOM- or EOM-ethers to their corresponding acetates and TMS-ethers under thermal conditions and microwave irradiation. These procedures were simple, rapid and the corresponding products were obtained in high yields. The catalyst exhibited remarkable reactivity and was reusable.",

keywords = "1-Butyl-methylimidazolium tetrachloroferrate, 12-Tungstophosphoric acid, Alkoxymethyl ether, Interconversion, Protection",

author = "I. Mohammadpoor-Baltork and M. Moghadam and S. Tangestaninejad and V. Mirkhani and Khosropour, \{A. R.\} and A. Mirjafari",

year = "2011",

month = jun,

doi = "10.1007/BF03249085",

language = "English",

volume = "8",

pages = "513--524",

journal = "Journal of the Iranian Chemical Society",

issn = "1735-207X",

publisher = "Springer Verlag",

number = "2",

}

TY - JOUR

T1 - H3PW12O40at the[bmim][FeCl4]

T2 - A green catalytic system for alkoxymethylation of alcohols and their one-pot interconversion to acetates and TMS-ethers

AU - Mohammadpoor-Baltork, I.

AU - Moghadam, M.

AU - Tangestaninejad, S.

AU - Mirkhani, V.

AU - Khosropour, A. R.

AU - Mirjafari, A.

PY - 2011/6

Y1 - 2011/6

N2 - 12-Tungstophosphoric acid immobilized on [bmim][FeCl4] was found to be an efficient catalyst for chemoselective methoxymethylation and ethxoymethylation of alcohols and also one-pot conversion of MOM- or EOM-ethers to their corresponding acetates and TMS-ethers under thermal conditions and microwave irradiation. These procedures were simple, rapid and the corresponding products were obtained in high yields. The catalyst exhibited remarkable reactivity and was reusable.

AB - 12-Tungstophosphoric acid immobilized on [bmim][FeCl4] was found to be an efficient catalyst for chemoselective methoxymethylation and ethxoymethylation of alcohols and also one-pot conversion of MOM- or EOM-ethers to their corresponding acetates and TMS-ethers under thermal conditions and microwave irradiation. These procedures were simple, rapid and the corresponding products were obtained in high yields. The catalyst exhibited remarkable reactivity and was reusable.

KW - 1-Butyl-methylimidazolium tetrachloroferrate

KW - 12-Tungstophosphoric acid

KW - Alkoxymethyl ether

KW - Interconversion

KW - Protection

UR - https://www.scopus.com/pages/publications/79957775277

U2 - 10.1007/BF03249085

DO - 10.1007/BF03249085

M3 - Article

SN - 1735-207X

VL - 8

SP - 513

EP - 524

JO - Journal of the Iranian Chemical Society

JF - Journal of the Iranian Chemical Society

IS - 2

ER -

H₃PW₁₂O₄₀at the[bmim][FeCl₄]: A green catalytic system for alkoxymethylation of alcohols and their one-pot interconversion to acetates and TMS-ethers

Abstract

Keywords

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