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Initial oxidation kinetics of copper (1 1 0) film investigated by in situ UHV-TEM

  • University of Pittsburgh

Research output: Contribution to journalArticlepeer-review

86 Scopus citations

Abstract

Previous studies of the initial stage of oxidation on clean single crystal of Cu(1 0 0) have been extended to the case of the Cu(1 1 0) surface. The dynamic observation of the nucleation and growth of Cu oxide by means of in situ ultra high vacuum transmission electron microscopy (UHV-TEM) shows a highly enhanced oxidation rate on Cu(1 1 0) surface as compared to Cu(1 0 0). The kinetic data on the nucleation and growth of the three-dimensional oxide islands agree well with our heteroepitaxial model of surface diffusion of oxygen.

Original languageEnglish
Pages (from-to)359-367
Number of pages9
JournalSurface Science
Volume531
Issue number3
DOIs
StatePublished - Jun 1 2003

Keywords

  • Copper
  • Electron microscopy
  • Nucleation
  • Oxidation
  • Surface diffusion

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