Intercalating oleylamines in graphite oxide

Kaikun Yang; Si Liang; Lianfeng Zou; Liwei Huang; Cheol Park; Lisheng Zhu; Jiye Fang; Qiang Fu; Howard Wang

doi:10.1021/la203769p

Intercalating oleylamines in graphite oxide

Kaikun Yang
, Si Liang
, Lianfeng Zou
, Liwei Huang
, Cheol Park
, Lisheng Zhu
, Jiye Fang
, Qiang Fu
, Howard Wang

Chemistry

Binghamton University

Institute for Materials Research
Sichuan University
National Institute of Aerospace
State University of New York Binghamton University

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Graphite oxide has been synthesized from raw graphite particles and been treated with various mass amounts of oleylamine as intercalants to form intercalation compounds. X-ray diffraction patterns reveal that the inter-sheet distances strongly depend on the graphite oxide to oleylamine mass ratios. The equilibrium-like behavior implies diffusion-dominated oleylamine adsorption on graphite oxide in solution and excluded volume intercalations among oleylamine-adsorbed graphite oxide during restacking. The intercalation compounds are soluble in organic solvents, and their applications in the fabrication of transparent and conductive coatings have been demonstrated.

Original language	English
Pages (from-to)	2904-2908
Number of pages	5
Journal	Langmuir
Volume	28
Issue number	5
DOIs	https://doi.org/10.1021/la203769p
State	Published - Feb 7 2012

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10.1021/la203769p

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abstract = "Graphite oxide has been synthesized from raw graphite particles and been treated with various mass amounts of oleylamine as intercalants to form intercalation compounds. X-ray diffraction patterns reveal that the inter-sheet distances strongly depend on the graphite oxide to oleylamine mass ratios. The equilibrium-like behavior implies diffusion-dominated oleylamine adsorption on graphite oxide in solution and excluded volume intercalations among oleylamine-adsorbed graphite oxide during restacking. The intercalation compounds are soluble in organic solvents, and their applications in the fabrication of transparent and conductive coatings have been demonstrated.",

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T1 - Intercalating oleylamines in graphite oxide

AU - Yang, Kaikun

AU - Liang, Si

AU - Zou, Lianfeng

AU - Huang, Liwei

AU - Park, Cheol

AU - Zhu, Lisheng

AU - Fang, Jiye

AU - Fu, Qiang

AU - Wang, Howard

PY - 2012/2/7

Y1 - 2012/2/7

N2 - Graphite oxide has been synthesized from raw graphite particles and been treated with various mass amounts of oleylamine as intercalants to form intercalation compounds. X-ray diffraction patterns reveal that the inter-sheet distances strongly depend on the graphite oxide to oleylamine mass ratios. The equilibrium-like behavior implies diffusion-dominated oleylamine adsorption on graphite oxide in solution and excluded volume intercalations among oleylamine-adsorbed graphite oxide during restacking. The intercalation compounds are soluble in organic solvents, and their applications in the fabrication of transparent and conductive coatings have been demonstrated.

AB - Graphite oxide has been synthesized from raw graphite particles and been treated with various mass amounts of oleylamine as intercalants to form intercalation compounds. X-ray diffraction patterns reveal that the inter-sheet distances strongly depend on the graphite oxide to oleylamine mass ratios. The equilibrium-like behavior implies diffusion-dominated oleylamine adsorption on graphite oxide in solution and excluded volume intercalations among oleylamine-adsorbed graphite oxide during restacking. The intercalation compounds are soluble in organic solvents, and their applications in the fabrication of transparent and conductive coatings have been demonstrated.

UR - https://www.scopus.com/pages/publications/84863076083

U2 - 10.1021/la203769p

DO - 10.1021/la203769p

M3 - Article

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SN - 0743-7463

VL - 28

SP - 2904

EP - 2908

JO - Langmuir

JF - Langmuir

IS - 5

ER -

Intercalating oleylamines in graphite oxide

Abstract

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