Ion-Directed Coordinative Polymerization of Copper(II) Pyridyl-Alcohol Complexes Through Thiane Functionalities

Sebastian Schmitz; Natalya V. Izarova; Claire Besson; Jan van Leusen; Paul Kögerler; Kirill Yu Monakhov

doi:10.1002/zaac.201800469

Ion-Directed Coordinative Polymerization of Copper(II) Pyridyl-Alcohol Complexes Through Thiane Functionalities

Sebastian Schmitz
, Natalya V. Izarova
, Claire Besson
, Jan van Leusen
, Paul Kögerler
, Kirill Yu Monakhov

Chemistry

Binghamton University

RWTH Aachen University
Jülich Research Centre
Leibniz Institute of Surface Engineering

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A mononuclear complex [Cu(HL·S) ₂ (NO ₃ ) ₂ ] (1) and a one- dimensional coordination polymer [Cu(HL·S)Cl ₂ ] _n (2) [HL·S = 4-(pyridin-2-ylmethyl)tetrahydro-2H-thiopyran-4-ol] showcase the structure-directing role of the counterions in their formation reaction: monodentate ligation of NO ₃ ^– and Cl ^– induces an octahedral (with two HL·S per Cu in 1) or trigonal-bipyramidal (with one HL·S per Cu in 2) Cu ^II coordination environment. In contrast to 1 exhibiting no coordinative metal–sulfur bonds in the crystal lattice (space group P2 ₁ /c), 2 (P2 ₁ /c) features intermolecular Cu–S contacts of 2.3188(7) Å. The coordination compounds are thermally stable up to ca. 160 °C. Whereas 1 demonstrates the spin-like behavior of an isolated central Cu ^II ion, compound 2 exhibits weak antiferromagnetic intra-chain coupling with J ≈ –2.1 cm ^–1 between neighboring Cu ^II ions.

Original language	English
Pages (from-to)	409-415
Number of pages	7
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	645
Issue number	4
DOIs	https://doi.org/10.1002/zaac.201800469
State	Published - Feb 28 2019

Keywords

Crystal structure
Magnetochemistry
Pyridyl-alcohol
Sulfur
Thio–copper bond

Access to Document

10.1002/zaac.201800469

Cite this

@article{3f9291ffd8814e8b9b22a1a9a2f9ab30,

title = "Ion-Directed Coordinative Polymerization of Copper(II) Pyridyl-Alcohol Complexes Through Thiane Functionalities",

abstract = " A mononuclear complex [Cu(HL·S) 2 (NO 3 ) 2 ] (1) and a one- dimensional coordination polymer [Cu(HL·S)Cl 2 ] n (2) [HL·S = 4-(pyridin-2-ylmethyl)tetrahydro-2H-thiopyran-4-ol] showcase the structure-directing role of the counterions in their formation reaction: monodentate ligation of NO 3 – and Cl – induces an octahedral (with two HL·S per Cu in 1) or trigonal-bipyramidal (with one HL·S per Cu in 2) Cu II coordination environment. In contrast to 1 exhibiting no coordinative metal–sulfur bonds in the crystal lattice (space group P2 1 /c), 2 (P2 1 /c) features intermolecular Cu–S contacts of 2.3188(7) {\AA}. The coordination compounds are thermally stable up to ca. 160 °C. Whereas 1 demonstrates the spin-like behavior of an isolated central Cu II ion, compound 2 exhibits weak antiferromagnetic intra-chain coupling with J ≈ –2.1 cm –1 between neighboring Cu II ions.",

keywords = "Crystal structure, Magnetochemistry, Pyridyl-alcohol, Sulfur, Thio–copper bond",

author = "Sebastian Schmitz and Izarova, \{Natalya V.\} and Claire Besson and \{van Leusen\}, Jan and Paul K{\"o}gerler and Monakhov, \{Kirill Yu\}",

note = "Publisher Copyright: {\textcopyright} 2019 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2019",

month = feb,

day = "28",

doi = "10.1002/zaac.201800469",

language = "English",

volume = "645",

pages = "409--415",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "4",

}

TY - JOUR

T1 - Ion-Directed Coordinative Polymerization of Copper(II) Pyridyl-Alcohol Complexes Through Thiane Functionalities

AU - Schmitz, Sebastian

AU - Izarova, Natalya V.

AU - Besson, Claire

AU - van Leusen, Jan

AU - Kögerler, Paul

AU - Monakhov, Kirill Yu

PY - 2019/2/28

Y1 - 2019/2/28

N2 - A mononuclear complex [Cu(HL·S) 2 (NO 3 ) 2 ] (1) and a one- dimensional coordination polymer [Cu(HL·S)Cl 2 ] n (2) [HL·S = 4-(pyridin-2-ylmethyl)tetrahydro-2H-thiopyran-4-ol] showcase the structure-directing role of the counterions in their formation reaction: monodentate ligation of NO 3 – and Cl – induces an octahedral (with two HL·S per Cu in 1) or trigonal-bipyramidal (with one HL·S per Cu in 2) Cu II coordination environment. In contrast to 1 exhibiting no coordinative metal–sulfur bonds in the crystal lattice (space group P2 1 /c), 2 (P2 1 /c) features intermolecular Cu–S contacts of 2.3188(7) Å. The coordination compounds are thermally stable up to ca. 160 °C. Whereas 1 demonstrates the spin-like behavior of an isolated central Cu II ion, compound 2 exhibits weak antiferromagnetic intra-chain coupling with J ≈ –2.1 cm –1 between neighboring Cu II ions.

AB - A mononuclear complex [Cu(HL·S) 2 (NO 3 ) 2 ] (1) and a one- dimensional coordination polymer [Cu(HL·S)Cl 2 ] n (2) [HL·S = 4-(pyridin-2-ylmethyl)tetrahydro-2H-thiopyran-4-ol] showcase the structure-directing role of the counterions in their formation reaction: monodentate ligation of NO 3 – and Cl – induces an octahedral (with two HL·S per Cu in 1) or trigonal-bipyramidal (with one HL·S per Cu in 2) Cu II coordination environment. In contrast to 1 exhibiting no coordinative metal–sulfur bonds in the crystal lattice (space group P2 1 /c), 2 (P2 1 /c) features intermolecular Cu–S contacts of 2.3188(7) Å. The coordination compounds are thermally stable up to ca. 160 °C. Whereas 1 demonstrates the spin-like behavior of an isolated central Cu II ion, compound 2 exhibits weak antiferromagnetic intra-chain coupling with J ≈ –2.1 cm –1 between neighboring Cu II ions.

KW - Crystal structure

KW - Magnetochemistry

KW - Pyridyl-alcohol

KW - Sulfur

KW - Thio–copper bond

UR - https://www.scopus.com/pages/publications/85060179480

U2 - 10.1002/zaac.201800469

DO - 10.1002/zaac.201800469

M3 - Article

SN - 0044-2313

VL - 645

SP - 409

EP - 415

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 4

ER -

Ion-Directed Coordinative Polymerization of Copper(II) Pyridyl-Alcohol Complexes Through Thiane Functionalities

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this