TY - CHAP
T1 - Li partitioning, diffusion and associated isotopic fractionation
T2 - theoretical and experimental insights
AU - Tomascak, Paul B.
AU - Magna, Tomáš
AU - Dohmen, Ralf
N1 - Publisher Copyright: © Springer International Publishing Switzerland 2016.
PY - 2016
Y1 - 2016
N2 - Laboratory experiments on the partitioning of elements and isotopes between various phases (minerals, fluids, and melts) at thermodynamic equilibrium are fundamental to the interpretation of geochemical data. We compile and discuss in this chapter the measured partition coefficients of Li and Li isotopes between various phases (mineral–melt, mineral–fluid, and mineral–mineral), and the measured diffusion coefficients of Li in minerals, fluids, and melts. Furthermore, we present and discuss consequences of diffusive fractionation of Li isotopes. Based on the information compiled for partitioning and diffusion behavior of Li, we finally discuss experiments on fluid–rock interaction with special emphasis on the behavior of Li.
AB - Laboratory experiments on the partitioning of elements and isotopes between various phases (minerals, fluids, and melts) at thermodynamic equilibrium are fundamental to the interpretation of geochemical data. We compile and discuss in this chapter the measured partition coefficients of Li and Li isotopes between various phases (mineral–melt, mineral–fluid, and mineral–mineral), and the measured diffusion coefficients of Li in minerals, fluids, and melts. Furthermore, we present and discuss consequences of diffusive fractionation of Li isotopes. Based on the information compiled for partitioning and diffusion behavior of Li, we finally discuss experiments on fluid–rock interaction with special emphasis on the behavior of Li.
UR - https://www.scopus.com/pages/publications/85040163627
U2 - 10.1007/978-3-319-01430-2_4
DO - 10.1007/978-3-319-01430-2_4
M3 - Chapter
T3 - Advances in Isotope Geochemistry
SP - 47
EP - 118
BT - Advances in Isotope Geochemistry
PB - Springer
ER -