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Lifetime measurements of interference-narrowed sodium Stark resonances

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Abstract

We report measurements of the temporal decay of sodium Stark resonances over regions of interference narrowing and compare with calculations using Wentzel-Kramers-Brillouin quantum-defect (WKB-QD) Stark theory. The measurements are performed with a beam of sodium atoms in a uniform electric field of 3.2 kV/cm excited via the 3 P2 state to 285 cm-1 (n*20) below the zero-field ionization threshold, and hence substantially above the classical saddle-point energy. For mixed states at level crossings, the discrete-continuum couplings interfere, yielding resonances that are stabilized against ionization over a small interval of the field. Measurements of the maximum lifetimes of m=1 levels here are not limited by laser bandwidth, as were our previous spectral observations of m=0 resonances. For three narrowing regions studied here, the observed maximum lifetime values of 127191 nsec are 1020 % less than values obtained from WKB-QD calculations, while experimental error limits are 5%. After considering estimates for competing processes, namely radiative decay and transfer by blackbody radiation, a slight discrepancy remains.

Original languageEnglish
Pages (from-to)3302-3312
Number of pages11
JournalPhysical Review A - Atomic, Molecular, and Optical Physics
Volume37
Issue number9
DOIs
StatePublished - 1988

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