Ligand effects on the aerobic oxidation of cyclohexene catalysed by aqua(phosphine)ruthenium(II) complexes

Carol A. Bessel; Randolph A. Leising; Kenneth J. Takeuchi

doi:10.1039/C39910000833

Ligand effects on the aerobic oxidation of cyclohexene catalysed by aqua(phosphine)ruthenium(II) complexes

Carol A. Bessel
, Randolph A. Leising
, Kenneth J. Takeuchi

Chemistry

Stony Brook University

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The multistep nature of the aerobic oxidation of cyclohexene catalysed by a series of aqua(phosphine)ruthenium(II) complexes can clearly be demonstrated from the correlation of catalyst turnovers with the rate constants of ligand substitution, and the correlation of catalyst turnovers with Hammett σ_p values.

Original language	English
Pages (from-to)	833-835
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/C39910000833
State	Published - 1991

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@article{2911ecdbb7a6493c926f9330ee9215b7,

title = "Ligand effects on the aerobic oxidation of cyclohexene catalysed by aqua(phosphine)ruthenium(II) complexes",

abstract = "The multistep nature of the aerobic oxidation of cyclohexene catalysed by a series of aqua(phosphine)ruthenium(II) complexes can clearly be demonstrated from the correlation of catalyst turnovers with the rate constants of ligand substitution, and the correlation of catalyst turnovers with Hammett σp values.",

author = "Bessel, \{Carol A.\} and Leising, \{Randolph A.\} and Takeuchi, \{Kenneth J.\}",

year = "1991",

doi = "10.1039/C39910000833",

language = "English",

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journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - Ligand effects on the aerobic oxidation of cyclohexene catalysed by aqua(phosphine)ruthenium(II) complexes

AU - Bessel, Carol A.

AU - Leising, Randolph A.

AU - Takeuchi, Kenneth J.

PY - 1991

Y1 - 1991

N2 - The multistep nature of the aerobic oxidation of cyclohexene catalysed by a series of aqua(phosphine)ruthenium(II) complexes can clearly be demonstrated from the correlation of catalyst turnovers with the rate constants of ligand substitution, and the correlation of catalyst turnovers with Hammett σp values.

AB - The multistep nature of the aerobic oxidation of cyclohexene catalysed by a series of aqua(phosphine)ruthenium(II) complexes can clearly be demonstrated from the correlation of catalyst turnovers with the rate constants of ligand substitution, and the correlation of catalyst turnovers with Hammett σp values.

UR - https://www.scopus.com/pages/publications/0012419948

U2 - 10.1039/C39910000833

DO - 10.1039/C39910000833

M3 - Article

SN - 0022-4936

SP - 833

EP - 835

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 12

ER -

Ligand effects on the aerobic oxidation of cyclohexene catalysed by aqua(phosphine)ruthenium(II) complexes

Abstract

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