LITHIUM INCORPORATION IN CRYSTALLINE AND AMORPHOUS CHALCOGENIDES: THERMODYNAMICS, MECHANISM AND STRUCTURE.

M. Stanley Whittingham

doi:10.1016/s0022-0728(81)80543-8

LITHIUM INCORPORATION IN CRYSTALLINE AND AMORPHOUS CHALCOGENIDES: THERMODYNAMICS, MECHANISM AND STRUCTURE.

M. Stanley Whittingham

Chemistry

Binghamton University

Research output: Contribution to conference › Paper › peer-review

5 Scopus citations

Abstract

The reaction of inorganic cathodes in lithium batteries can occur by two major mechanisms, displacement or insertion. At ambient temperatures the latter tend to show varying degrees of reversibility whereas the former tend to be irreversible. A discussion is presented of the critical roles that thermodynamics and crystal structure play in the reaction path and hence the reversibility of lithium reactions. Emphasis is placed on the titanium sulfides, vanadium diselenide and the molybdenum sulfides.

Original language	English
Pages	229-239
Number of pages	11
DOIs	https://doi.org/10.1016/s0022-0728(81)80543-8
State	Published - 1981
Event	Stud Phys Theor Chem 15, Prog in Electrochem, Proc of the Aust Electrochem Conf, 5th - Perth, Aust Duration: Aug 18 1980 → Aug 22 1980

Conference

Conference	Stud Phys Theor Chem 15, Prog in Electrochem, Proc of the Aust Electrochem Conf, 5th
City	Perth, Aust
Period	08/18/80 → 08/22/80

Access to Document

10.1016/s0022-0728(81)80543-8

Cite this

@conference{c9f84cf6ec384d06918613aa2ebf2da1,

title = "LITHIUM INCORPORATION IN CRYSTALLINE AND AMORPHOUS CHALCOGENIDES: THERMODYNAMICS, MECHANISM AND STRUCTURE.",

abstract = "The reaction of inorganic cathodes in lithium batteries can occur by two major mechanisms, displacement or insertion. At ambient temperatures the latter tend to show varying degrees of reversibility whereas the former tend to be irreversible. A discussion is presented of the critical roles that thermodynamics and crystal structure play in the reaction path and hence the reversibility of lithium reactions. Emphasis is placed on the titanium sulfides, vanadium diselenide and the molybdenum sulfides.",

author = "Whittingham, \{M. Stanley\}",

year = "1981",

doi = "10.1016/s0022-0728(81)80543-8",

language = "English",

pages = "229--239",

note = "Stud Phys Theor Chem 15, Prog in Electrochem, Proc of the Aust Electrochem Conf, 5th ; Conference date: 18-08-1980 Through 22-08-1980",

}

TY - CONF

T1 - LITHIUM INCORPORATION IN CRYSTALLINE AND AMORPHOUS CHALCOGENIDES

T2 - Stud Phys Theor Chem 15, Prog in Electrochem, Proc of the Aust Electrochem Conf, 5th

AU - Whittingham, M. Stanley

PY - 1981

Y1 - 1981

N2 - The reaction of inorganic cathodes in lithium batteries can occur by two major mechanisms, displacement or insertion. At ambient temperatures the latter tend to show varying degrees of reversibility whereas the former tend to be irreversible. A discussion is presented of the critical roles that thermodynamics and crystal structure play in the reaction path and hence the reversibility of lithium reactions. Emphasis is placed on the titanium sulfides, vanadium diselenide and the molybdenum sulfides.

AB - The reaction of inorganic cathodes in lithium batteries can occur by two major mechanisms, displacement or insertion. At ambient temperatures the latter tend to show varying degrees of reversibility whereas the former tend to be irreversible. A discussion is presented of the critical roles that thermodynamics and crystal structure play in the reaction path and hence the reversibility of lithium reactions. Emphasis is placed on the titanium sulfides, vanadium diselenide and the molybdenum sulfides.

UR - https://www.scopus.com/pages/publications/0019703909

U2 - 10.1016/s0022-0728(81)80543-8

DO - 10.1016/s0022-0728(81)80543-8

M3 - Paper

SP - 229

EP - 239

Y2 - 18 August 1980 through 22 August 1980

ER -

LITHIUM INCORPORATION IN CRYSTALLINE AND AMORPHOUS CHALCOGENIDES: THERMODYNAMICS, MECHANISM AND STRUCTURE.

Abstract

Conference

Access to Document

Other files and links

Fingerprint

Cite this