Magnetic properties of vanadium oxide nanotubes, nanourchins, and nanorods

Chris Jacobs; Megan Roppolo; Kristin Butterworth; Chunmei Ban; Natasha A. Chernova; M. Stanley Whittingham

doi:10.1557/proc-988-0988-qq03-19

Magnetic properties of vanadium oxide nanotubes, nanourchins, and nanorods

Chris Jacobs
, Megan Roppolo
, Kristin Butterworth
, Chunmei Ban
, Natasha A. Chernova
, M. Stanley Whittingham

Chemistry

Binghamton University

State University of New York Binghamton University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

3 Scopus citations

Abstract

A better understanding of magnetic interactions, charge distribution, and redox properties of vanadium oxide nanotubes (VONTs) is necessary for accurate structure and mechanism of formation determination. Magnetic properties have been determined for pristine and lithiated VONTs and for the VONTs arranged in nanourchin morphology. Presence of paramagnetic V⁴⁺ ions and V ⁴⁺ ions coupled in magnetic dimers is found, and their amounts are estimated. Both lithiation and change of morphology to nanourchin destroy the spin-gap behavior, which indicate changes in charge distribution. No ferromagnetic response is observed in lithiated VONTs. Magnetic properties of vanadium oxide nanorods with δ-V₄O₁₀ structure are also characterized.

Original language	English
Title of host publication	Solid-State Chemistry of Inorganic Materials VI
Publisher	Materials Research Society
Pages	200-205
Number of pages	6
ISBN (Print)	9781604234336
DOIs	https://doi.org/10.1557/proc-988-0988-qq03-19
State	Published - 2006
Event	2006 MRS Fall Meeting - Boston, MA, United States Duration: Nov 27 2006 → Dec 1 2006

Publication series

Name	Materials Research Society Symposium Proceedings
Volume	988

Conference

Conference	2006 MRS Fall Meeting
Country/Territory	United States
City	Boston, MA
Period	11/27/06 → 12/1/06

Access to Document

10.1557/proc-988-0988-qq03-19

Cite this

Jacobs, C., Roppolo, M., Butterworth, K., Ban, C., Chernova, N. A., & Whittingham, M. S. (2006). Magnetic properties of vanadium oxide nanotubes, nanourchins, and nanorods. In Solid-State Chemistry of Inorganic Materials VI (pp. 200-205). (Materials Research Society Symposium Proceedings; Vol. 988). Materials Research Society. https://doi.org/10.1557/proc-988-0988-qq03-19

@inproceedings{6fcec1a9184c466bbff8d209043c54f7,

title = "Magnetic properties of vanadium oxide nanotubes, nanourchins, and nanorods",

abstract = "A better understanding of magnetic interactions, charge distribution, and redox properties of vanadium oxide nanotubes (VONTs) is necessary for accurate structure and mechanism of formation determination. Magnetic properties have been determined for pristine and lithiated VONTs and for the VONTs arranged in nanourchin morphology. Presence of paramagnetic V4+ ions and V 4+ ions coupled in magnetic dimers is found, and their amounts are estimated. Both lithiation and change of morphology to nanourchin destroy the spin-gap behavior, which indicate changes in charge distribution. No ferromagnetic response is observed in lithiated VONTs. Magnetic properties of vanadium oxide nanorods with δ-V4O10 structure are also characterized.",

author = "Chris Jacobs and Megan Roppolo and Kristin Butterworth and Chunmei Ban and Chernova, \{Natasha A.\} and Whittingham, \{M. Stanley\}",

year = "2006",

doi = "10.1557/proc-988-0988-qq03-19",

language = "English",

isbn = "9781604234336",

series = "Materials Research Society Symposium Proceedings",

publisher = "Materials Research Society",

pages = "200--205",

booktitle = "Solid-State Chemistry of Inorganic Materials VI",

note = "2006 MRS Fall Meeting ; Conference date: 27-11-2006 Through 01-12-2006",

}

Jacobs, C, Roppolo, M, Butterworth, K, Ban, C, Chernova, NA & Whittingham, MS 2006, Magnetic properties of vanadium oxide nanotubes, nanourchins, and nanorods. in Solid-State Chemistry of Inorganic Materials VI. Materials Research Society Symposium Proceedings, vol. 988, Materials Research Society, pp. 200-205, 2006 MRS Fall Meeting, Boston, MA, United States, 11/27/06. https://doi.org/10.1557/proc-988-0988-qq03-19

Magnetic properties of vanadium oxide nanotubes, nanourchins, and nanorods. / Jacobs, Chris; Roppolo, Megan; Butterworth, Kristin et al.
Solid-State Chemistry of Inorganic Materials VI. Materials Research Society, 2006. p. 200-205 (Materials Research Society Symposium Proceedings; Vol. 988).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Magnetic properties of vanadium oxide nanotubes, nanourchins, and nanorods

AU - Jacobs, Chris

AU - Roppolo, Megan

AU - Butterworth, Kristin

AU - Ban, Chunmei

AU - Chernova, Natasha A.

AU - Whittingham, M. Stanley

PY - 2006

Y1 - 2006

N2 - A better understanding of magnetic interactions, charge distribution, and redox properties of vanadium oxide nanotubes (VONTs) is necessary for accurate structure and mechanism of formation determination. Magnetic properties have been determined for pristine and lithiated VONTs and for the VONTs arranged in nanourchin morphology. Presence of paramagnetic V4+ ions and V 4+ ions coupled in magnetic dimers is found, and their amounts are estimated. Both lithiation and change of morphology to nanourchin destroy the spin-gap behavior, which indicate changes in charge distribution. No ferromagnetic response is observed in lithiated VONTs. Magnetic properties of vanadium oxide nanorods with δ-V4O10 structure are also characterized.

AB - A better understanding of magnetic interactions, charge distribution, and redox properties of vanadium oxide nanotubes (VONTs) is necessary for accurate structure and mechanism of formation determination. Magnetic properties have been determined for pristine and lithiated VONTs and for the VONTs arranged in nanourchin morphology. Presence of paramagnetic V4+ ions and V 4+ ions coupled in magnetic dimers is found, and their amounts are estimated. Both lithiation and change of morphology to nanourchin destroy the spin-gap behavior, which indicate changes in charge distribution. No ferromagnetic response is observed in lithiated VONTs. Magnetic properties of vanadium oxide nanorods with δ-V4O10 structure are also characterized.

UR - https://www.scopus.com/pages/publications/41549139708

U2 - 10.1557/proc-988-0988-qq03-19

DO - 10.1557/proc-988-0988-qq03-19

M3 - Conference contribution

SN - 9781604234336

T3 - Materials Research Society Symposium Proceedings

SP - 200

EP - 205

BT - Solid-State Chemistry of Inorganic Materials VI

PB - Materials Research Society

T2 - 2006 MRS Fall Meeting

Y2 - 27 November 2006 through 1 December 2006

ER -

Magnetic properties of vanadium oxide nanotubes, nanourchins, and nanorods

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