Magnetic structure and properties of NaFeSO 4F and NaCoSO 4F

B. C. Melot; G. Rousse; J. N. Chotard; M. C. Kemei; J. Rodríguez-Carvajal; J. M. Tarascon

doi:10.1103/PhysRevB.85.094415

Magnetic structure and properties of NaFeSO ₄F and NaCoSO ₄F

B. C. Melot
, G. Rousse
, J. N. Chotard
, M. C. Kemei
, J. Rodríguez-Carvajal
, J. M. Tarascon

Chemistry

Binghamton University

Institut de Minéralogie et de Physique des Milieux Condensés
Université de Picardie Jules Verne
University of California at Santa Barbara
Institut Laue-Langevin

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

NaFeSO ₄F and NaCoSO ₄F crystallize in the maxwellite crystal structure and consist of one-dimensional chains of corner-sharing MO ₄F ₂ octahedra linked together through F atoms sitting in a trans configuration with respect to each other. Magnetic susceptibility measurements and low-temperature powder neutron diffraction indicate that both the Fe- and Co-based phases establish G-type antiferromagnetic ground states below 36 and 29 K, respectively. We discuss the obtained magnetic structure in the context of the local anisotropy of the two magnetic ions.

Original language	English
Article number	094415
Journal	Physical Review B - Condensed Matter and Materials Physics
Volume	85
Issue number	9
DOIs	https://doi.org/10.1103/PhysRevB.85.094415
State	Published - Mar 12 2012

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10.1103/PhysRevB.85.094415

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title = "Magnetic structure and properties of NaFeSO 4F and NaCoSO 4F",

abstract = "NaFeSO 4F and NaCoSO 4F crystallize in the maxwellite crystal structure and consist of one-dimensional chains of corner-sharing MO 4F 2 octahedra linked together through F atoms sitting in a trans configuration with respect to each other. Magnetic susceptibility measurements and low-temperature powder neutron diffraction indicate that both the Fe- and Co-based phases establish G-type antiferromagnetic ground states below 36 and 29 K, respectively. We discuss the obtained magnetic structure in the context of the local anisotropy of the two magnetic ions.",

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T1 - Magnetic structure and properties of NaFeSO 4F and NaCoSO 4F

AU - Melot, B. C.

AU - Rousse, G.

AU - Chotard, J. N.

AU - Kemei, M. C.

AU - Rodríguez-Carvajal, J.

AU - Tarascon, J. M.

PY - 2012/3/12

Y1 - 2012/3/12

N2 - NaFeSO 4F and NaCoSO 4F crystallize in the maxwellite crystal structure and consist of one-dimensional chains of corner-sharing MO 4F 2 octahedra linked together through F atoms sitting in a trans configuration with respect to each other. Magnetic susceptibility measurements and low-temperature powder neutron diffraction indicate that both the Fe- and Co-based phases establish G-type antiferromagnetic ground states below 36 and 29 K, respectively. We discuss the obtained magnetic structure in the context of the local anisotropy of the two magnetic ions.

AB - NaFeSO 4F and NaCoSO 4F crystallize in the maxwellite crystal structure and consist of one-dimensional chains of corner-sharing MO 4F 2 octahedra linked together through F atoms sitting in a trans configuration with respect to each other. Magnetic susceptibility measurements and low-temperature powder neutron diffraction indicate that both the Fe- and Co-based phases establish G-type antiferromagnetic ground states below 36 and 29 K, respectively. We discuss the obtained magnetic structure in the context of the local anisotropy of the two magnetic ions.

UR - https://www.scopus.com/pages/publications/84858379383

U2 - 10.1103/PhysRevB.85.094415

DO - 10.1103/PhysRevB.85.094415

M3 - Article

SN - 1098-0121

VL - 85

JO - Physical Review B - Condensed Matter and Materials Physics

JF - Physical Review B - Condensed Matter and Materials Physics

IS - 9

M1 - 094415

ER -

Magnetic structure and properties of NaFeSO ₄F and NaCoSO ₄F

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