Manganese dioxides as cathodes for lithium rechargeable cells: The stability challenge

M. Stanley Whittingham; Peter Y. Zavalij

doi:10.1016/S0167-2738(00)00626-3

Manganese dioxides as cathodes for lithium rechargeable cells: The stability challenge

M. Stanley Whittingham
, Peter Y. Zavalij

Chemistry

Binghamton University

State University of New York Binghamton University

Research output: Contribution to journal › Conference article › peer-review

50 Scopus citations

Abstract

A wide range of manganese oxides is under study for possible use as the cathode of high energy density batteries. The spinel, LiMn₂O₄, although the most studied has a relatively low energy density and appears unstable under charge. This review emphasizes non-spinel oxides, in particular those with layered or tunnel structures that offer enhanced behavior in lithium ion and lithium polymer cells. A major focus is on stabilizing these manganese oxide structures against conversion to the spinel phase.

Original language	English
Pages (from-to)	109-115
Number of pages	7
Journal	Solid State Ionics
Volume	131
Issue number	1
DOIs	https://doi.org/10.1016/S0167-2738(00)00626-3
State	Published - Jun 1 2000
Event	The 1998 International Workshop on Interfacially Controlled Functional Materials: Electrical and Chemical Properties - Schloss Ringberg, Ger Duration: Mar 8 1998 → Mar 13 1998

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abstract = "A wide range of manganese oxides is under study for possible use as the cathode of high energy density batteries. The spinel, LiMn2O4, although the most studied has a relatively low energy density and appears unstable under charge. This review emphasizes non-spinel oxides, in particular those with layered or tunnel structures that offer enhanced behavior in lithium ion and lithium polymer cells. A major focus is on stabilizing these manganese oxide structures against conversion to the spinel phase.",

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AU - Zavalij, Peter Y.

PY - 2000/6/1

Y1 - 2000/6/1

N2 - A wide range of manganese oxides is under study for possible use as the cathode of high energy density batteries. The spinel, LiMn2O4, although the most studied has a relatively low energy density and appears unstable under charge. This review emphasizes non-spinel oxides, in particular those with layered or tunnel structures that offer enhanced behavior in lithium ion and lithium polymer cells. A major focus is on stabilizing these manganese oxide structures against conversion to the spinel phase.

AB - A wide range of manganese oxides is under study for possible use as the cathode of high energy density batteries. The spinel, LiMn2O4, although the most studied has a relatively low energy density and appears unstable under charge. This review emphasizes non-spinel oxides, in particular those with layered or tunnel structures that offer enhanced behavior in lithium ion and lithium polymer cells. A major focus is on stabilizing these manganese oxide structures against conversion to the spinel phase.

UR - https://www.scopus.com/pages/publications/0033716865

U2 - 10.1016/S0167-2738(00)00626-3

DO - 10.1016/S0167-2738(00)00626-3

M3 - Conference article

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JO - Solid State Ionics

JF - Solid State Ionics

IS - 1

Y2 - 8 March 1998 through 13 March 1998

ER -

Manganese dioxides as cathodes for lithium rechargeable cells: The stability challenge

Abstract

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