Mechanism of the anionic polymerization of lactones, initiated by intercalation graphite compounds

Iliya Rashkov; Ivan Panayotov; Ivan Gitsov

doi:10.1007/BF01045246

Mechanism of the anionic polymerization of lactones, initiated by intercalation graphite compounds

Iliya Rashkov
, Ivan Panayotov
, Ivan Gitsov

Chemistry

College of Environmental Science & Forestry

Bulgarian Academy of Sciences

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The anionic polymerization of β-propiolactone (PL)oxethane-2-one, pivalolactone (PVL) - 3,3-dimethyloxethane-2-one and e{open}-caprolactone (CL) - oxepane-2-one, initiated by binary and ternary intercalation compounds (IC) of lithium and potassium in graphite is investigated. The polymerization is carried out in bulk or in xylene. It is established that the lactones penetrate in IC and polymerize in their interlayer spacings. The polymerization causes a delamination of IC. High polymers of the lactones can be obtained by the action of some IC investigated.

Original language	English
Pages (from-to)	97-103
Number of pages	7
Journal	Polymer Bulletin
Volume	4
Issue number	1-2
DOIs	https://doi.org/10.1007/BF01045246
State	Published - Jan 1981

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title = "Mechanism of the anionic polymerization of lactones, initiated by intercalation graphite compounds",

abstract = "The anionic polymerization of β-propiolactone (PL)oxethane-2-one, pivalolactone (PVL) - 3,3-dimethyloxethane-2-one and e\{open\}-caprolactone (CL) - oxepane-2-one, initiated by binary and ternary intercalation compounds (IC) of lithium and potassium in graphite is investigated. The polymerization is carried out in bulk or in xylene. It is established that the lactones penetrate in IC and polymerize in their interlayer spacings. The polymerization causes a delamination of IC. High polymers of the lactones can be obtained by the action of some IC investigated.",

author = "Iliya Rashkov and Ivan Panayotov and Ivan Gitsov",

year = "1981",

month = jan,

doi = "10.1007/BF01045246",

language = "English",

volume = "4",

pages = "97--103",

journal = "Polymer Bulletin",

issn = "0170-0839",

publisher = "Springer Verlag",

number = "1-2",

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TY - JOUR

T1 - Mechanism of the anionic polymerization of lactones, initiated by intercalation graphite compounds

AU - Rashkov, Iliya

AU - Panayotov, Ivan

AU - Gitsov, Ivan

PY - 1981/1

Y1 - 1981/1

N2 - The anionic polymerization of β-propiolactone (PL)oxethane-2-one, pivalolactone (PVL) - 3,3-dimethyloxethane-2-one and e{open}-caprolactone (CL) - oxepane-2-one, initiated by binary and ternary intercalation compounds (IC) of lithium and potassium in graphite is investigated. The polymerization is carried out in bulk or in xylene. It is established that the lactones penetrate in IC and polymerize in their interlayer spacings. The polymerization causes a delamination of IC. High polymers of the lactones can be obtained by the action of some IC investigated.

AB - The anionic polymerization of β-propiolactone (PL)oxethane-2-one, pivalolactone (PVL) - 3,3-dimethyloxethane-2-one and e{open}-caprolactone (CL) - oxepane-2-one, initiated by binary and ternary intercalation compounds (IC) of lithium and potassium in graphite is investigated. The polymerization is carried out in bulk or in xylene. It is established that the lactones penetrate in IC and polymerize in their interlayer spacings. The polymerization causes a delamination of IC. High polymers of the lactones can be obtained by the action of some IC investigated.

UR - https://www.scopus.com/pages/publications/0019478414

U2 - 10.1007/BF01045246

DO - 10.1007/BF01045246

M3 - Article

SN - 0170-0839

VL - 4

SP - 97

EP - 103

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 1-2

ER -

Mechanism of the anionic polymerization of lactones, initiated by intercalation graphite compounds

Abstract

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