Mesoscale chiroptics of rhythmic precipitates

Erica Gunn; Ryan Sours; Jason B. Benedict; Werner Kaminsky; Bart Kahr

doi:10.1021/ja065139

Mesoscale chiroptics of rhythmic precipitates

Erica Gunn
, Ryan Sours
, Jason B. Benedict
, Werner Kaminsky
, Bart Kahr

Chemistry

University at Buffalo

University of Washington

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

Rhythmic precipitates of centrosymmetric phthalic acid were analyzed by a square-wave mechanically modulated circular extinction imaging microscope. Spherulites were bisected into square-millimeter sized heterochiral domains that are a consequence of circular intensity differential scattering of left and right circularly polarized light. The dissymmetry and chiral amplification indicated optically was confirmed in the microtexture established by atomic force and scanning electron microscopies.

Original language	English
Pages (from-to)	14234-14235
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	44
DOIs	https://doi.org/10.1021/ja065139
State	Published - Nov 8 2006

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10.1021/ja065139

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title = "Mesoscale chiroptics of rhythmic precipitates",

abstract = "Rhythmic precipitates of centrosymmetric phthalic acid were analyzed by a square-wave mechanically modulated circular extinction imaging microscope. Spherulites were bisected into square-millimeter sized heterochiral domains that are a consequence of circular intensity differential scattering of left and right circularly polarized light. The dissymmetry and chiral amplification indicated optically was confirmed in the microtexture established by atomic force and scanning electron microscopies.",

author = "Erica Gunn and Ryan Sours and Benedict, \{Jason B.\} and Werner Kaminsky and Bart Kahr",

year = "2006",

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doi = "10.1021/ja065139",

language = "English",

volume = "128",

pages = "14234--14235",

journal = "Journal of the American Chemical Society",

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T1 - Mesoscale chiroptics of rhythmic precipitates

AU - Gunn, Erica

AU - Sours, Ryan

AU - Benedict, Jason B.

AU - Kaminsky, Werner

AU - Kahr, Bart

PY - 2006/11/8

Y1 - 2006/11/8

N2 - Rhythmic precipitates of centrosymmetric phthalic acid were analyzed by a square-wave mechanically modulated circular extinction imaging microscope. Spherulites were bisected into square-millimeter sized heterochiral domains that are a consequence of circular intensity differential scattering of left and right circularly polarized light. The dissymmetry and chiral amplification indicated optically was confirmed in the microtexture established by atomic force and scanning electron microscopies.

AB - Rhythmic precipitates of centrosymmetric phthalic acid were analyzed by a square-wave mechanically modulated circular extinction imaging microscope. Spherulites were bisected into square-millimeter sized heterochiral domains that are a consequence of circular intensity differential scattering of left and right circularly polarized light. The dissymmetry and chiral amplification indicated optically was confirmed in the microtexture established by atomic force and scanning electron microscopies.

UR - https://www.scopus.com/pages/publications/33750694611

U2 - 10.1021/ja065139

DO - 10.1021/ja065139

M3 - Article

SN - 0002-7863

VL - 128

SP - 14234

EP - 14235

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 44

ER -

Mesoscale chiroptics of rhythmic precipitates

Abstract

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