Mixed chloride/phosphine complexes of the dirhenium core. 8. Synthesis and crystal structure of the quadruply bonded dirhenium(III) anion [Re2Cl7(PMe3)]-

F. A. Cotton; E. V. Dikarev; M. A. Petrukhina

doi:10.1021/ic010504d

Mixed chloride/phosphine complexes of the dirhenium core. 8. Synthesis and crystal structure of the quadruply bonded dirhenium(III) anion [Re₂Cl₇(PMe₃)]^-

Chemistry

University at Albany

Texas A&M University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A new dirhenium(III) anion [Re₂Cl₇(PMe₃)]^- completing the series of complexes Re₂Cl_8-x(PMe₃)_x (x = l, 2, 3, and 4) with the basic monodentate phosphine PMe₃ has prepared by a one-electron oxidation of the dirhenium(II,III) complex Re₂Cl₅(PMe₃)₃ in the presence of [Buⁿ₄N]Cl as a chloride source. It was isolated in the form of the compound [Buⁿ₄N]₄ [Re₂Cl₇(PMe₃)]₂ [Re₂-Cl₈]·2CH₂Cl₂ and was structurally characterized.

Original language	English
Pages (from-to)	5716-5718
Number of pages	3
Journal	Inorganic Chemistry
Volume	40
Issue number	22
DOIs	https://doi.org/10.1021/ic010504d
State	Published - Oct 22 2001

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title = "Mixed chloride/phosphine complexes of the dirhenium core. 8. Synthesis and crystal structure of the quadruply bonded dirhenium(III) anion [Re2Cl7(PMe3)]-",

abstract = "A new dirhenium(III) anion [Re2Cl7(PMe3)]- completing the series of complexes Re2Cl8-x(PMe3)x (x = l, 2, 3, and 4) with the basic monodentate phosphine PMe3 has prepared by a one-electron oxidation of the dirhenium(II,III) complex Re2Cl5(PMe3)3 in the presence of [Bun4N]Cl as a chloride source. It was isolated in the form of the compound [Bun4N]4 [Re2Cl7(PMe3)]2 [Re2-Cl8]·2CH2Cl2 and was structurally characterized.",

author = "Cotton, \{F. A.\} and Dikarev, \{E. V.\} and Petrukhina, \{M. A.\}",

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T1 - Mixed chloride/phosphine complexes of the dirhenium core. 8. Synthesis and crystal structure of the quadruply bonded dirhenium(III) anion [Re2Cl7(PMe3)]-

AU - Cotton, F. A.

AU - Dikarev, E. V.

AU - Petrukhina, M. A.

PY - 2001/10/22

Y1 - 2001/10/22

N2 - A new dirhenium(III) anion [Re2Cl7(PMe3)]- completing the series of complexes Re2Cl8-x(PMe3)x (x = l, 2, 3, and 4) with the basic monodentate phosphine PMe3 has prepared by a one-electron oxidation of the dirhenium(II,III) complex Re2Cl5(PMe3)3 in the presence of [Bun4N]Cl as a chloride source. It was isolated in the form of the compound [Bun4N]4 [Re2Cl7(PMe3)]2 [Re2-Cl8]·2CH2Cl2 and was structurally characterized.

AB - A new dirhenium(III) anion [Re2Cl7(PMe3)]- completing the series of complexes Re2Cl8-x(PMe3)x (x = l, 2, 3, and 4) with the basic monodentate phosphine PMe3 has prepared by a one-electron oxidation of the dirhenium(II,III) complex Re2Cl5(PMe3)3 in the presence of [Bun4N]Cl as a chloride source. It was isolated in the form of the compound [Bun4N]4 [Re2Cl7(PMe3)]2 [Re2-Cl8]·2CH2Cl2 and was structurally characterized.

UR - https://www.scopus.com/pages/publications/0035935082

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DO - 10.1021/ic010504d

M3 - Article

C2 - 11599977

SN - 0020-1669

VL - 40

SP - 5716

EP - 5718

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

ER -

Mixed chloride/phosphine complexes of the dirhenium core. 8. Synthesis and crystal structure of the quadruply bonded dirhenium(III) anion [Re₂Cl₇(PMe₃)]^-

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