Molecular hydrogen assisted transport of H atoms

Rubik Asatryan

doi:10.1016/j.cplett.2010.09.003

Molecular hydrogen assisted transport of H atoms

Rubik Asatryan

Department of Mechanical and Aerospace Engineering

University at Buffalo

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Transport of hydrogen atoms plays a key role in chemical and biological processes involving metabolism of molecular hydrogen. Several 'gas-phase' and more intricate organometallic models (mimics of the hydrogenase enzyme) are developed to show the intriguing role of the molecular hydrogen as a third party in the pass-on transfer of hydrogen atoms. This hydrogen assisted transport (HAT) mechanism is based on the current understanding of the hydrogen exchange reactions and it is believed to be applicable to certain H/D-isotope exchange processes and remote transport of H-atoms.

Original language	English
Pages (from-to)	263-269
Number of pages	7
Journal	Chemical Physics Letters
Volume	498
Issue number	4-6
DOIs	https://doi.org/10.1016/j.cplett.2010.09.003
State	Published - Oct 8 2010

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10.1016/j.cplett.2010.09.003

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title = "Molecular hydrogen assisted transport of H atoms",

abstract = "Transport of hydrogen atoms plays a key role in chemical and biological processes involving metabolism of molecular hydrogen. Several 'gas-phase' and more intricate organometallic models (mimics of the hydrogenase enzyme) are developed to show the intriguing role of the molecular hydrogen as a third party in the pass-on transfer of hydrogen atoms. This hydrogen assisted transport (HAT) mechanism is based on the current understanding of the hydrogen exchange reactions and it is believed to be applicable to certain H/D-isotope exchange processes and remote transport of H-atoms.",

author = "Rubik Asatryan",

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AU - Asatryan, Rubik

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Y1 - 2010/10/8

N2 - Transport of hydrogen atoms plays a key role in chemical and biological processes involving metabolism of molecular hydrogen. Several 'gas-phase' and more intricate organometallic models (mimics of the hydrogenase enzyme) are developed to show the intriguing role of the molecular hydrogen as a third party in the pass-on transfer of hydrogen atoms. This hydrogen assisted transport (HAT) mechanism is based on the current understanding of the hydrogen exchange reactions and it is believed to be applicable to certain H/D-isotope exchange processes and remote transport of H-atoms.

AB - Transport of hydrogen atoms plays a key role in chemical and biological processes involving metabolism of molecular hydrogen. Several 'gas-phase' and more intricate organometallic models (mimics of the hydrogenase enzyme) are developed to show the intriguing role of the molecular hydrogen as a third party in the pass-on transfer of hydrogen atoms. This hydrogen assisted transport (HAT) mechanism is based on the current understanding of the hydrogen exchange reactions and it is believed to be applicable to certain H/D-isotope exchange processes and remote transport of H-atoms.

UR - https://www.scopus.com/pages/publications/77957315515

U2 - 10.1016/j.cplett.2010.09.003

DO - 10.1016/j.cplett.2010.09.003

M3 - Article

SN - 0009-2614

VL - 498

SP - 263

EP - 269

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4-6

ER -

Molecular hydrogen assisted transport of H atoms

Abstract

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