Nitrosamide, (H2NNO), formation within [(NO)m(NH3)n]+ clusters: Theory and experiment

Dong Nam Shin; Marek Freindorf; Thomas R. Furlani; Robert L. DeLeon; James F. Garvey

doi:10.1016/j.ijms.2005.09.006

Nitrosamide, (H₂NNO), formation within [(NO)_m(NH₃)_n]⁺ clusters: Theory and experiment

Dong Nam Shin
, Marek Freindorf
, Thomas R. Furlani
, Robert L. DeLeon
, James F. Garvey

University at Buffalo

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The generation of nitrosamide (H₂NNO) molecules mediated by the cluster environment of the NO/NH₃ cluster system has been explored, employing both multiphoton ionization time-of-flight mass spectrometry and ab initio calculations. This combined approach indicates that the H₂NNO species is viable and can exist within cluster ions of the type [H₂NNO···NO··· NH₃]⁺. Possible mechanisms for formation of the H₂NNO species are discussed.

Original language	English
Pages (from-to)	28-38
Number of pages	11
Journal	International Journal of Mass Spectrometry
Volume	255-256
Issue number	1-3
DOIs	https://doi.org/10.1016/j.ijms.2005.09.006
State	Published - Sep 1 2006

Keywords

Ammonia
Gas phase clusters
Ion-molecule chemistry
Nitric oxide
Nitrosamide

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10.1016/j.ijms.2005.09.006

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title = "Nitrosamide, (H2NNO), formation within [(NO)m(NH3)n]+ clusters: Theory and experiment",

abstract = "The generation of nitrosamide (H2NNO) molecules mediated by the cluster environment of the NO/NH3 cluster system has been explored, employing both multiphoton ionization time-of-flight mass spectrometry and ab initio calculations. This combined approach indicates that the H2NNO species is viable and can exist within cluster ions of the type [H2NNO···NO··· NH3]+. Possible mechanisms for formation of the H2NNO species are discussed.",

keywords = "Ammonia, Gas phase clusters, Ion-molecule chemistry, Nitric oxide, Nitrosamide",

author = "Shin, \{Dong Nam\} and Marek Freindorf and Furlani, \{Thomas R.\} and DeLeon, \{Robert L.\} and Garvey, \{James F.\}",

year = "2006",

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doi = "10.1016/j.ijms.2005.09.006",

language = "English",

volume = "255-256",

pages = "28--38",

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TY - JOUR

T1 - Nitrosamide, (H2NNO), formation within [(NO)m(NH3)n]+ clusters

T2 - Theory and experiment

AU - Shin, Dong Nam

AU - Freindorf, Marek

AU - Furlani, Thomas R.

AU - DeLeon, Robert L.

AU - Garvey, James F.

PY - 2006/9/1

Y1 - 2006/9/1

N2 - The generation of nitrosamide (H2NNO) molecules mediated by the cluster environment of the NO/NH3 cluster system has been explored, employing both multiphoton ionization time-of-flight mass spectrometry and ab initio calculations. This combined approach indicates that the H2NNO species is viable and can exist within cluster ions of the type [H2NNO···NO··· NH3]+. Possible mechanisms for formation of the H2NNO species are discussed.

AB - The generation of nitrosamide (H2NNO) molecules mediated by the cluster environment of the NO/NH3 cluster system has been explored, employing both multiphoton ionization time-of-flight mass spectrometry and ab initio calculations. This combined approach indicates that the H2NNO species is viable and can exist within cluster ions of the type [H2NNO···NO··· NH3]+. Possible mechanisms for formation of the H2NNO species are discussed.

KW - Ammonia

KW - Gas phase clusters

KW - Ion-molecule chemistry

KW - Nitric oxide

KW - Nitrosamide

UR - https://www.scopus.com/pages/publications/33747386911

U2 - 10.1016/j.ijms.2005.09.006

DO - 10.1016/j.ijms.2005.09.006

M3 - Article

SN - 1387-3806

VL - 255-256

SP - 28

EP - 38

JO - International Journal of Mass Spectrometry

JF - International Journal of Mass Spectrometry

IS - 1-3

ER -

Nitrosamide, (H₂NNO), formation within [(NO)_m(NH₃)_n]⁺ clusters: Theory and experiment

Abstract

Keywords

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