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On the issue of work function tuning of nickel silicide gates

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

The mechanism of work function tuning in NixSiy gates was investigated critically. Furthermore, the role of the underlying dielectric (SiO2 and high-k materials) was also evaluated and it was found that the work function tuning mechanism strongly depends upon the concentration of SiO2 in the dielectric. Ternary alloy silicides NixTa 1-xSi and NixPt1-xSi were investigated as possible gates for NMOS and PMOS application repectively. Φm of 4.27eV and 5.1eV was achieved for the cases of Ta rich and Pt rich suicides on SiO2. However , the window of Φm range reduced as hafnium was added to the dielectric such that for the case of HfO2 dielectric, the range reduced to 200meV. We attribute this to Fermi level pinning due to increase in Hf+Si bonds. Critical investigation of the role of dielectric-metal gate interface was carried out. Results of varying the Ni and Si composition on SiO2, HfO2 and HfSiOx dielectrics and resulting variation of EOT and Φm are compared. We report dielectric surface related possible phase modulation of Ni xSiy gates. To understand the co-relation of EOT variation with work function of the metal gate, top interface of HfSiOx was modulated and the results of such modulation affected increase in the Φm tuning. copyright The Electrochemical Society.

Original languageEnglish
Title of host publicationPhysics and Technology of High-k Gate Dielectrics 4
PublisherElectrochemical Society Inc.
Pages317-331
Number of pages15
Edition3
ISBN (Electronic)1566775035
DOIs
StatePublished - 2006
EventPhysics and Technology of High-k Gate Dielectrics 4 - 210th Electrochemical Society Meeting - Cancun, Mexico
Duration: Oct 29 2006Nov 3 2006

Publication series

NameECS Transactions
Number3
Volume3

Conference

ConferencePhysics and Technology of High-k Gate Dielectrics 4 - 210th Electrochemical Society Meeting
Country/TerritoryMexico
CityCancun
Period10/29/0611/3/06

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