Pb2.63Cd2V3O12, a cation-deficient garnet-type vanadate

Alexander A. Tsirlin; Evgeny V. Dikarev; Yuri A. Velikodny; Roman V. Shpanchenko; Evgeny V. Antipov

doi:10.1107/S0108270107021233

Pb_2.63Cd₂V₃O₁₂, a cation-deficient garnet-type vanadate

Alexander A. Tsirlin
, Evgeny V. Dikarev
, Yuri A. Velikodny
, Roman V. Shpanchenko
, Evgeny V. Antipov

Chemistry

University at Albany

Lomonosov Moscow State University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

In the crystal structure of the cation-deficient garnet Pb2.63Cd2V3O12 (lead cadmium vanadium oxide), the Cd and V atoms fully occupy octa-hedral and tetra-hedral sites, respectively, whereas the Pb atoms partially occupy a dodeca-hedral site. The total Pb and Cd content indicates that vanadium is slightly reduced from the +5 oxidation state.

Original language	English
Pages (from-to)	i40-i42
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	63
Issue number	7
DOIs	https://doi.org/10.1107/S0108270107021233
State	Published - Jun 14 2007

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title = "Pb2.63Cd2V3O12, a cation-deficient garnet-type vanadate",

abstract = "In the crystal structure of the cation-deficient garnet Pb2.63Cd2V3O12 (lead cadmium vanadium oxide), the Cd and V atoms fully occupy octa-hedral and tetra-hedral sites, respectively, whereas the Pb atoms partially occupy a dodeca-hedral site. The total Pb and Cd content indicates that vanadium is slightly reduced from the +5 oxidation state.",

author = "Tsirlin, \{Alexander A.\} and Dikarev, \{Evgeny V.\} and Velikodny, \{Yuri A.\} and Shpanchenko, \{Roman V.\} and Antipov, \{Evgeny V.\}",

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T1 - Pb2.63Cd2V3O12, a cation-deficient garnet-type vanadate

AU - Tsirlin, Alexander A.

AU - Dikarev, Evgeny V.

AU - Velikodny, Yuri A.

AU - Shpanchenko, Roman V.

AU - Antipov, Evgeny V.

PY - 2007/6/14

Y1 - 2007/6/14

N2 - In the crystal structure of the cation-deficient garnet Pb2.63Cd2V3O12 (lead cadmium vanadium oxide), the Cd and V atoms fully occupy octa-hedral and tetra-hedral sites, respectively, whereas the Pb atoms partially occupy a dodeca-hedral site. The total Pb and Cd content indicates that vanadium is slightly reduced from the +5 oxidation state.

AB - In the crystal structure of the cation-deficient garnet Pb2.63Cd2V3O12 (lead cadmium vanadium oxide), the Cd and V atoms fully occupy octa-hedral and tetra-hedral sites, respectively, whereas the Pb atoms partially occupy a dodeca-hedral site. The total Pb and Cd content indicates that vanadium is slightly reduced from the +5 oxidation state.

UR - https://www.scopus.com/pages/publications/34547440417

U2 - 10.1107/S0108270107021233

DO - 10.1107/S0108270107021233

M3 - Article

SN - 0108-2701

VL - 63

SP - i40-i42

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 7

ER -

Pb_2.63Cd₂V₃O₁₂, a cation-deficient garnet-type vanadate

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