Phonon bands in a π-electron charge-transfer complex

Freeman P. Chen; Paras N. Prasad

doi:10.1016/0038-1098(77)90352-0

Phonon bands in a π-electron charge-transfer complex

Freeman P. Chen
, Paras N. Prasad

Chemistry

University at Buffalo

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Phonon bands in mixed-stack π-electron charge-transfer complexes are investigated using Raman spectroscopy. Specifically, the Raman phonon spectra of naphthalene: antimony trichloride system is discussed in detail. The effect of the substitution of the donor and the acceptor is used to examine relative amplitudes of various motions on the donor and the acceptor. Phonon delocalization is investigated using various mixed crystals containing donor and acceptor impurities. The result obtained is discussed in terms of two models: (i) the giant molecule model, and (ii) the sublattice model.

Original language	English
Pages (from-to)	871-873
Number of pages	3
Journal	Solid State Communications
Volume	21
Issue number	9
DOIs	https://doi.org/10.1016/0038-1098(77)90352-0
State	Published - Mar 1977

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title = "Phonon bands in a π-electron charge-transfer complex",

abstract = "Phonon bands in mixed-stack π-electron charge-transfer complexes are investigated using Raman spectroscopy. Specifically, the Raman phonon spectra of naphthalene: antimony trichloride system is discussed in detail. The effect of the substitution of the donor and the acceptor is used to examine relative amplitudes of various motions on the donor and the acceptor. Phonon delocalization is investigated using various mixed crystals containing donor and acceptor impurities. The result obtained is discussed in terms of two models: (i) the giant molecule model, and (ii) the sublattice model.",

author = "Chen, \{Freeman P.\} and Prasad, \{Paras N.\}",

year = "1977",

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doi = "10.1016/0038-1098(77)90352-0",

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volume = "21",

pages = "871--873",

journal = "Solid State Communications",

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TY - JOUR

T1 - Phonon bands in a π-electron charge-transfer complex

AU - Chen, Freeman P.

AU - Prasad, Paras N.

PY - 1977/3

Y1 - 1977/3

N2 - Phonon bands in mixed-stack π-electron charge-transfer complexes are investigated using Raman spectroscopy. Specifically, the Raman phonon spectra of naphthalene: antimony trichloride system is discussed in detail. The effect of the substitution of the donor and the acceptor is used to examine relative amplitudes of various motions on the donor and the acceptor. Phonon delocalization is investigated using various mixed crystals containing donor and acceptor impurities. The result obtained is discussed in terms of two models: (i) the giant molecule model, and (ii) the sublattice model.

AB - Phonon bands in mixed-stack π-electron charge-transfer complexes are investigated using Raman spectroscopy. Specifically, the Raman phonon spectra of naphthalene: antimony trichloride system is discussed in detail. The effect of the substitution of the donor and the acceptor is used to examine relative amplitudes of various motions on the donor and the acceptor. Phonon delocalization is investigated using various mixed crystals containing donor and acceptor impurities. The result obtained is discussed in terms of two models: (i) the giant molecule model, and (ii) the sublattice model.

UR - https://www.scopus.com/pages/publications/0017465739

U2 - 10.1016/0038-1098(77)90352-0

DO - 10.1016/0038-1098(77)90352-0

M3 - Article

SN - 0038-1098

VL - 21

SP - 871

EP - 873

JO - Solid State Communications

JF - Solid State Communications

IS - 9

ER -

Phonon bands in a π-electron charge-transfer complex

Abstract

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