Phosphorodithioate-functionalized ionic liquids: Synthesis and physicochemical properties characterization

Zachary Shultz; Jamie C. Gaitor; Rachel D. Burton; Matthew Regner; Yinghong Sheng; Arsalan Mirjafari

doi:10.1016/j.molliq.2018.11.166

Phosphorodithioate-functionalized ionic liquids: Synthesis and physicochemical properties characterization

Zachary Shultz
, Jamie C. Gaitor
, Rachel D. Burton
, Matthew Regner
, Yinghong Sheng
, Arsalan Mirjafari

Chemistry

SUNY Oswego

Florida Gulf Coast University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

This study focuses on preparation and characterization of physicochemical properties of a series of phosphorodithioate-bearing ionic liquids. They displayed low glass transition temperatures, high thermal stability, and were hydrophobic in character. The results of their ligation capability toward Pd(II) via ³¹P NMR spectroscopy is also presented. The synthetic strategy has the potential to impart (EtO)₂P(=S)S functionality to ionic liquids by providing the flexibility to incorporate long linkers and task-specific anion to enhance hydrophobicity.

Original language	English
Pages (from-to)	334-337
Number of pages	4
Journal	Journal of Molecular Liquids
Volume	276
DOIs	https://doi.org/10.1016/j.molliq.2018.11.166
State	Published - Feb 15 2019

Keywords

Ionic liquids
Palladium binding
Phosphorodithioate
Task-specific ionic liquids

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10.1016/j.molliq.2018.11.166

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title = "Phosphorodithioate-functionalized ionic liquids: Synthesis and physicochemical properties characterization",

abstract = "This study focuses on preparation and characterization of physicochemical properties of a series of phosphorodithioate-bearing ionic liquids. They displayed low glass transition temperatures, high thermal stability, and were hydrophobic in character. The results of their ligation capability toward Pd(II) via 31P NMR spectroscopy is also presented. The synthetic strategy has the potential to impart (EtO)2P(=S)S functionality to ionic liquids by providing the flexibility to incorporate long linkers and task-specific anion to enhance hydrophobicity.",

keywords = "Ionic liquids, Palladium binding, Phosphorodithioate, Task-specific ionic liquids",

author = "Zachary Shultz and Gaitor, \{Jamie C.\} and Burton, \{Rachel D.\} and Matthew Regner and Yinghong Sheng and Arsalan Mirjafari",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

year = "2019",

month = feb,

day = "15",

doi = "10.1016/j.molliq.2018.11.166",

language = "English",

volume = "276",

pages = "334--337",

journal = "Journal of Molecular Liquids",

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TY - JOUR

T1 - Phosphorodithioate-functionalized ionic liquids

T2 - Synthesis and physicochemical properties characterization

AU - Shultz, Zachary

AU - Gaitor, Jamie C.

AU - Burton, Rachel D.

AU - Regner, Matthew

AU - Sheng, Yinghong

AU - Mirjafari, Arsalan

PY - 2019/2/15

Y1 - 2019/2/15

N2 - This study focuses on preparation and characterization of physicochemical properties of a series of phosphorodithioate-bearing ionic liquids. They displayed low glass transition temperatures, high thermal stability, and were hydrophobic in character. The results of their ligation capability toward Pd(II) via 31P NMR spectroscopy is also presented. The synthetic strategy has the potential to impart (EtO)2P(=S)S functionality to ionic liquids by providing the flexibility to incorporate long linkers and task-specific anion to enhance hydrophobicity.

AB - This study focuses on preparation and characterization of physicochemical properties of a series of phosphorodithioate-bearing ionic liquids. They displayed low glass transition temperatures, high thermal stability, and were hydrophobic in character. The results of their ligation capability toward Pd(II) via 31P NMR spectroscopy is also presented. The synthetic strategy has the potential to impart (EtO)2P(=S)S functionality to ionic liquids by providing the flexibility to incorporate long linkers and task-specific anion to enhance hydrophobicity.

KW - Ionic liquids

KW - Palladium binding

KW - Phosphorodithioate

KW - Task-specific ionic liquids

UR - https://www.scopus.com/pages/publications/85057735426

U2 - 10.1016/j.molliq.2018.11.166

DO - 10.1016/j.molliq.2018.11.166

M3 - Article

SN - 0167-7322

VL - 276

SP - 334

EP - 337

JO - Journal of Molecular Liquids

JF - Journal of Molecular Liquids

ER -

Phosphorodithioate-functionalized ionic liquids: Synthesis and physicochemical properties characterization

Abstract

Keywords

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