Photochemistry of benzoin acetate in cyclodextrin media

Nageshwer Rao Bantu; Thomas G. Kotch; Alistair J. Lees

doi:10.1016/S0040-4039(00)60340-4

Photochemistry of benzoin acetate in cyclodextrin media

Nageshwer Rao Bantu
, Thomas G. Kotch
, Alistair J. Lees

Acad Affairs Prov VP

Binghamton University

State University of New York Binghamton University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Photolyses of benzoin acetate 1 in organic solvents produce a non-selective mixture of type I products (3/2-5) and photocyclization product 2, while in aqueous cyclodextrin (CD) solutions and in solid CD complexes, a remarkable selectivity for photocyclization product 2 is observed. A Cage effect has been invoked to rationalize the unusual alteration of photobehaviour of 1 by CD.

Original language	English
Pages (from-to)	2039-2042
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	13
DOIs	https://doi.org/10.1016/S0040-4039(00)60340-4
State	Published - Mar 26 1993

Access to Document

10.1016/S0040-4039(00)60340-4

Cite this

@article{a3acca1b455046ecbe5bc9f717fe10be,

title = "Photochemistry of benzoin acetate in cyclodextrin media",

abstract = "Photolyses of benzoin acetate 1 in organic solvents produce a non-selective mixture of type I products (3/2-5) and photocyclization product 2, while in aqueous cyclodextrin (CD) solutions and in solid CD complexes, a remarkable selectivity for photocyclization product 2 is observed. A Cage effect has been invoked to rationalize the unusual alteration of photobehaviour of 1 by CD.",

author = "Bantu, \{Nageshwer Rao\} and Kotch, \{Thomas G.\} and Lees, \{Alistair J.\}",

year = "1993",

month = mar,

day = "26",

doi = "10.1016/S0040-4039(00)60340-4",

language = "English",

volume = "34",

pages = "2039--2042",

journal = "Tetrahedron Letters",

issn = "0040-4039",

number = "13",

}

TY - JOUR

T1 - Photochemistry of benzoin acetate in cyclodextrin media

AU - Bantu, Nageshwer Rao

AU - Kotch, Thomas G.

AU - Lees, Alistair J.

PY - 1993/3/26

Y1 - 1993/3/26

N2 - Photolyses of benzoin acetate 1 in organic solvents produce a non-selective mixture of type I products (3/2-5) and photocyclization product 2, while in aqueous cyclodextrin (CD) solutions and in solid CD complexes, a remarkable selectivity for photocyclization product 2 is observed. A Cage effect has been invoked to rationalize the unusual alteration of photobehaviour of 1 by CD.

AB - Photolyses of benzoin acetate 1 in organic solvents produce a non-selective mixture of type I products (3/2-5) and photocyclization product 2, while in aqueous cyclodextrin (CD) solutions and in solid CD complexes, a remarkable selectivity for photocyclization product 2 is observed. A Cage effect has been invoked to rationalize the unusual alteration of photobehaviour of 1 by CD.

UR - https://www.scopus.com/pages/publications/0027474638

U2 - 10.1016/S0040-4039(00)60340-4

DO - 10.1016/S0040-4039(00)60340-4

M3 - Article

SN - 0040-4039

VL - 34

SP - 2039

EP - 2042

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 13

ER -

Photochemistry of benzoin acetate in cyclodextrin media

Abstract

Access to Document

Other files and links

Fingerprint

Cite this