Polymerization in poly(ethylene oxide) gels. Anionic polymerization of methylmethacrylate initiated by t-BuOK

Ch Tsvetanov; D. Dotcheva; I. Gitsov; Ch Novakov

Polymerization in poly(ethylene oxide) gels. Anionic polymerization of methylmethacrylate initiated by t-BuOK

Ch Tsvetanov
, D. Dotcheva
, I. Gitsov
, Ch Novakov

Chemistry

College of Environmental Science & Forestry

Bulgarian Academy of Sciences

Research output: Contribution to journal › Conference article › peer-review

2 Scopus citations

Abstract

The aim of this work is to investigate the polymerization of MMA initiated by the complex PEO gel.t-BuOK in toluene. The influence of the reaction conditions on the yield, molecular weight characteristics and microstructure of the polymers formed is studied as well. The results are compared with those obtained during the polymerization of MMA under the action of t-BuOK complexed with cryptand [222]. The results obtained show that the anionic polymerization of MMA initiated by the complex PEO-gel/t-BuOK proceeds with considerably higher yields than the process initiated only by t-BuOK.

Original language	English
Pages (from-to)	98-99
Number of pages	2
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	29
Issue number	2
State	Published - Sep 1988
Event	Polymer Preprints - American Chemical Society - Los Angeles, CA, USA Duration: Sep 25 1988 → Sep 30 1988

Cite this

@article{c14e79158eb043f4bfb236004e12e08d,

title = "Polymerization in poly(ethylene oxide) gels. Anionic polymerization of methylmethacrylate initiated by t-BuOK",

abstract = "The aim of this work is to investigate the polymerization of MMA initiated by the complex PEO gel.t-BuOK in toluene. The influence of the reaction conditions on the yield, molecular weight characteristics and microstructure of the polymers formed is studied as well. The results are compared with those obtained during the polymerization of MMA under the action of t-BuOK complexed with cryptand [222]. The results obtained show that the anionic polymerization of MMA initiated by the complex PEO-gel/t-BuOK proceeds with considerably higher yields than the process initiated only by t-BuOK.",

author = "Ch Tsvetanov and D. Dotcheva and I. Gitsov and Ch Novakov",

year = "1988",

month = sep,

language = "English",

volume = "29",

pages = "98--99",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

issn = "0032-3934",

number = "2",

note = "Polymer Preprints - American Chemical Society ; Conference date: 25-09-1988 Through 30-09-1988",

}

TY - JOUR

T1 - Polymerization in poly(ethylene oxide) gels. Anionic polymerization of methylmethacrylate initiated by t-BuOK

AU - Tsvetanov, Ch

AU - Dotcheva, D.

AU - Gitsov, I.

AU - Novakov, Ch

PY - 1988/9

Y1 - 1988/9

N2 - The aim of this work is to investigate the polymerization of MMA initiated by the complex PEO gel.t-BuOK in toluene. The influence of the reaction conditions on the yield, molecular weight characteristics and microstructure of the polymers formed is studied as well. The results are compared with those obtained during the polymerization of MMA under the action of t-BuOK complexed with cryptand [222]. The results obtained show that the anionic polymerization of MMA initiated by the complex PEO-gel/t-BuOK proceeds with considerably higher yields than the process initiated only by t-BuOK.

AB - The aim of this work is to investigate the polymerization of MMA initiated by the complex PEO gel.t-BuOK in toluene. The influence of the reaction conditions on the yield, molecular weight characteristics and microstructure of the polymers formed is studied as well. The results are compared with those obtained during the polymerization of MMA under the action of t-BuOK complexed with cryptand [222]. The results obtained show that the anionic polymerization of MMA initiated by the complex PEO-gel/t-BuOK proceeds with considerably higher yields than the process initiated only by t-BuOK.

UR - https://www.scopus.com/pages/publications/0024070403

M3 - Conference article

SN - 0032-3934

VL - 29

SP - 98

EP - 99

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 2

T2 - Polymer Preprints - American Chemical Society

Y2 - 25 September 1988 through 30 September 1988

ER -

Polymerization in poly(ethylene oxide) gels. Anionic polymerization of methylmethacrylate initiated by t-BuOK

Abstract

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