Radiofrequency spectroscopy of DCCD: Deuterium quadrupole coupling in acetylene

Robert L. DeLeon; John S. Muenter

doi:10.1016/0022-2852(87)90071-3

Radiofrequency spectroscopy of DCCD: Deuterium quadrupole coupling in acetylene

Robert L. DeLeon
, John S. Muenter

Center for Computational Research

University at Buffalo

University of Rochester

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Molecular beam electric resonance spectroscopy has been used to observe the P(16)e and P(16)f transitions in the ν₅-ν₄ band of dideutero acetylene. Hyperfine transitions were resolved in the P(16)e case, providing deuterium quadrupole coupling and spin rotation information. The hyperfine properties are essentially the same for ν₄, J = 16 and ν₅, J = 15 with eQq = 209(1) kHz and C = -0.42(2) kHz. This information is compared with other measurements of deuterium quadrupole coupling in acetylene.

Original language	English
Pages (from-to)	13-18
Number of pages	6
Journal	Journal of Molecular Spectroscopy
Volume	126
Issue number	1
DOIs	https://doi.org/10.1016/0022-2852(87)90071-3
State	Published - Nov 1987

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title = "Radiofrequency spectroscopy of DCCD: Deuterium quadrupole coupling in acetylene",

abstract = "Molecular beam electric resonance spectroscopy has been used to observe the P(16)e and P(16)f transitions in the ν5-ν4 band of dideutero acetylene. Hyperfine transitions were resolved in the P(16)e case, providing deuterium quadrupole coupling and spin rotation information. The hyperfine properties are essentially the same for ν4, J = 16 and ν5, J = 15 with eQq = 209(1) kHz and C = -0.42(2) kHz. This information is compared with other measurements of deuterium quadrupole coupling in acetylene.",

author = "DeLeon, \{Robert L.\} and Muenter, \{John S.\}",

year = "1987",

month = nov,

doi = "10.1016/0022-2852(87)90071-3",

language = "English",

volume = "126",

pages = "13--18",

journal = "Journal of Molecular Spectroscopy",

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publisher = "Academic Press Inc.",

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TY - JOUR

T1 - Radiofrequency spectroscopy of DCCD

T2 - Deuterium quadrupole coupling in acetylene

AU - DeLeon, Robert L.

AU - Muenter, John S.

PY - 1987/11

Y1 - 1987/11

N2 - Molecular beam electric resonance spectroscopy has been used to observe the P(16)e and P(16)f transitions in the ν5-ν4 band of dideutero acetylene. Hyperfine transitions were resolved in the P(16)e case, providing deuterium quadrupole coupling and spin rotation information. The hyperfine properties are essentially the same for ν4, J = 16 and ν5, J = 15 with eQq = 209(1) kHz and C = -0.42(2) kHz. This information is compared with other measurements of deuterium quadrupole coupling in acetylene.

AB - Molecular beam electric resonance spectroscopy has been used to observe the P(16)e and P(16)f transitions in the ν5-ν4 band of dideutero acetylene. Hyperfine transitions were resolved in the P(16)e case, providing deuterium quadrupole coupling and spin rotation information. The hyperfine properties are essentially the same for ν4, J = 16 and ν5, J = 15 with eQq = 209(1) kHz and C = -0.42(2) kHz. This information is compared with other measurements of deuterium quadrupole coupling in acetylene.

UR - https://www.scopus.com/pages/publications/11544278837

U2 - 10.1016/0022-2852(87)90071-3

DO - 10.1016/0022-2852(87)90071-3

M3 - Article

SN - 0022-2852

VL - 126

SP - 13

EP - 18

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

IS - 1

ER -

Radiofrequency spectroscopy of DCCD: Deuterium quadrupole coupling in acetylene

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