Reaction of metal carbonyl hydrides with decacarbonyldimanganese (Mn2(CO)10): radical reactions initiated by room light

Paula L. Bogdan; Andrew Wong; Jim D. Atwood

doi:10.1016/S0022-328X(00)90281-X

Reaction of metal carbonyl hydrides with decacarbonyldimanganese (Mn₂(CO)₁₀): radical reactions initiated by room light

Paula L. Bogdan
, Andrew Wong
, Jim D. Atwood

Chemistry

University at Buffalo

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

We have investigated the room light initiated reactions of HFeCp(CO)PPh₃ or HMoCp(CO)₂PPh₃ with Mn₂(CO)₁₀. In the reaction with the iron hydride we have observed six products and in the reaction with molybdenum hydride we have observed eight products. The nature of the products strongly suggests reactions of seventeen-electron complexes. The number of products show that recombinations of the seventeen-electron species occur with very low activation barriers, showing very little selectivity.

Original language	English
Pages (from-to)	185-191
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	229
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)90281-X
State	Published - Apr 20 1982

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title = "Reaction of metal carbonyl hydrides with decacarbonyldimanganese (Mn2(CO)10): radical reactions initiated by room light",

abstract = "We have investigated the room light initiated reactions of HFeCp(CO)PPh3 or HMoCp(CO)2PPh3 with Mn2(CO)10. In the reaction with the iron hydride we have observed six products and in the reaction with molybdenum hydride we have observed eight products. The nature of the products strongly suggests reactions of seventeen-electron complexes. The number of products show that recombinations of the seventeen-electron species occur with very low activation barriers, showing very little selectivity.",

author = "Bogdan, \{Paula L.\} and Andrew Wong and Atwood, \{Jim D.\}",

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T1 - Reaction of metal carbonyl hydrides with decacarbonyldimanganese (Mn2(CO)10)

T2 - radical reactions initiated by room light

AU - Bogdan, Paula L.

AU - Wong, Andrew

AU - Atwood, Jim D.

PY - 1982/4/20

Y1 - 1982/4/20

N2 - We have investigated the room light initiated reactions of HFeCp(CO)PPh3 or HMoCp(CO)2PPh3 with Mn2(CO)10. In the reaction with the iron hydride we have observed six products and in the reaction with molybdenum hydride we have observed eight products. The nature of the products strongly suggests reactions of seventeen-electron complexes. The number of products show that recombinations of the seventeen-electron species occur with very low activation barriers, showing very little selectivity.

AB - We have investigated the room light initiated reactions of HFeCp(CO)PPh3 or HMoCp(CO)2PPh3 with Mn2(CO)10. In the reaction with the iron hydride we have observed six products and in the reaction with molybdenum hydride we have observed eight products. The nature of the products strongly suggests reactions of seventeen-electron complexes. The number of products show that recombinations of the seventeen-electron species occur with very low activation barriers, showing very little selectivity.

UR - https://www.scopus.com/pages/publications/0010953416

U2 - 10.1016/S0022-328X(00)90281-X

DO - 10.1016/S0022-328X(00)90281-X

M3 - Article

SN - 0022-328X

VL - 229

SP - 185

EP - 191

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Reaction of metal carbonyl hydrides with decacarbonyldimanganese (Mn₂(CO)₁₀): radical reactions initiated by room light

Abstract

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