Reactions of Samarium Atoms in Inert and Reactive Matrices

Werner E. Klotzbücher; Marina A. Petrukhina; Gleb B. Sergeev

doi:10.1070/MC1994v004n01ABEH000323

Reactions of Samarium Atoms in Inert and Reactive Matrices

Werner E. Klotzbücher
, Marina A. Petrukhina
, Gleb B. Sergeev

Chemistry

University at Albany

Max Planck Institute for Chemical Energy Conversion
Lomonosov Moscow State University

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Cocondensation of samarium vapour with inert gases at cryogenic temperatures yields isolated samarium atoms and small clusters, while in complementary depositions with CO and N₂ novel carbonyl and dinitrogen complexes are formed. Surprisingly, ‘naked’ samarium atoms can be observed at 9 K in pure dinitrogen.

Original language	English
Pages (from-to)	5-7
Number of pages	3
Journal	Mendeleev Communications
Volume	4
Issue number	1
DOIs	https://doi.org/10.1070/MC1994v004n01ABEH000323
State	Published - 1994

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title = "Reactions of Samarium Atoms in Inert and Reactive Matrices",

abstract = "Cocondensation of samarium vapour with inert gases at cryogenic temperatures yields isolated samarium atoms and small clusters, while in complementary depositions with CO and N2 novel carbonyl and dinitrogen complexes are formed. Surprisingly, {\textquoteleft}naked{\textquoteright} samarium atoms can be observed at 9 K in pure dinitrogen.",

author = "Klotzb{\"u}cher, \{Werner E.\} and Petrukhina, \{Marina A.\} and Sergeev, \{Gleb B.\}",

year = "1994",

doi = "10.1070/MC1994v004n01ABEH000323",

language = "English",

volume = "4",

pages = "5--7",

journal = "Mendeleev Communications",

issn = "0959-9436",

publisher = "Mendeleevskie Soobshcheniya",

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T1 - Reactions of Samarium Atoms in Inert and Reactive Matrices

AU - Klotzbücher, Werner E.

AU - Petrukhina, Marina A.

AU - Sergeev, Gleb B.

PY - 1994

Y1 - 1994

N2 - Cocondensation of samarium vapour with inert gases at cryogenic temperatures yields isolated samarium atoms and small clusters, while in complementary depositions with CO and N2 novel carbonyl and dinitrogen complexes are formed. Surprisingly, ‘naked’ samarium atoms can be observed at 9 K in pure dinitrogen.

AB - Cocondensation of samarium vapour with inert gases at cryogenic temperatures yields isolated samarium atoms and small clusters, while in complementary depositions with CO and N2 novel carbonyl and dinitrogen complexes are formed. Surprisingly, ‘naked’ samarium atoms can be observed at 9 K in pure dinitrogen.

UR - https://www.scopus.com/pages/publications/85013813540

U2 - 10.1070/MC1994v004n01ABEH000323

DO - 10.1070/MC1994v004n01ABEH000323

M3 - Article

SN - 0959-9436

VL - 4

SP - 5

EP - 7

JO - Mendeleev Communications

JF - Mendeleev Communications

IS - 1

ER -

Reactions of Samarium Atoms in Inert and Reactive Matrices

Abstract

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