Reduction of isocyanates and carbodiimides via hydrosilylation

Iwao Ojima; Shin ichi Inaba

doi:10.1016/S0022-328X(00)84400-9

Reduction of isocyanates and carbodiimides via hydrosilylation

Iwao Ojima
, Shin ichi Inaba

Chemistry

Stony Brook University

Sagami Chemical Research Institute

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

The hydrosilylation of isocyanates is promoted by palladium catalysts and affords N-silylformamides or C-silylamides. The orientation of the reaction depended upon the structure of isocyanates. The reaction of carbodiimides with silicon hydrides, catalyzed by PdCl₂ or (Ph₃P)₃RhCl, required higher temperatures to give N-silylformamidines. The adducts obtained in these reactions are precursors to formamides, formamidines, and their N-acetyl derivatives.

Original language	English
Pages (from-to)	97-111
Number of pages	15
Journal	Journal of Organometallic Chemistry
Volume	140
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)84400-9
State	Published - Oct 25 1977

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title = "Reduction of isocyanates and carbodiimides via hydrosilylation",

abstract = "The hydrosilylation of isocyanates is promoted by palladium catalysts and affords N-silylformamides or C-silylamides. The orientation of the reaction depended upon the structure of isocyanates. The reaction of carbodiimides with silicon hydrides, catalyzed by PdCl2 or (Ph3P)3RhCl, required higher temperatures to give N-silylformamidines. The adducts obtained in these reactions are precursors to formamides, formamidines, and their N-acetyl derivatives.",

author = "Iwao Ojima and Inaba, \{Shin ichi\}",

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T1 - Reduction of isocyanates and carbodiimides via hydrosilylation

AU - Ojima, Iwao

AU - Inaba, Shin ichi

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Y1 - 1977/10/25

N2 - The hydrosilylation of isocyanates is promoted by palladium catalysts and affords N-silylformamides or C-silylamides. The orientation of the reaction depended upon the structure of isocyanates. The reaction of carbodiimides with silicon hydrides, catalyzed by PdCl2 or (Ph3P)3RhCl, required higher temperatures to give N-silylformamidines. The adducts obtained in these reactions are precursors to formamides, formamidines, and their N-acetyl derivatives.

AB - The hydrosilylation of isocyanates is promoted by palladium catalysts and affords N-silylformamides or C-silylamides. The orientation of the reaction depended upon the structure of isocyanates. The reaction of carbodiimides with silicon hydrides, catalyzed by PdCl2 or (Ph3P)3RhCl, required higher temperatures to give N-silylformamidines. The adducts obtained in these reactions are precursors to formamides, formamidines, and their N-acetyl derivatives.

UR - https://www.scopus.com/pages/publications/3142768933

U2 - 10.1016/S0022-328X(00)84400-9

DO - 10.1016/S0022-328X(00)84400-9

M3 - Article

SN - 0022-328X

VL - 140

SP - 97

EP - 111

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Reduction of isocyanates and carbodiimides via hydrosilylation

Abstract

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